动态化学与材料和非晶物理新关联——金属有机框架玻璃的挑战、进展与新机遇

doi:10.6023/A22120508

化学学报 ›› 2023, Vol. 81 ›› Issue (3): 246-252.DOI: 10.6023/A22120508 上一篇下一篇

研究展望

动态化学与材料和非晶物理新关联——金属有机框架玻璃的挑战、进展与新机遇

殷政^a^,^b^,^*(), 赵英博^c^,^*(), 曾明华^a^,^*()

a 广西师范大学化学与药学学院药用资源化学与药物分子工程省部共建国家重点实验室桂林 541004
b 陕西科技大学化学与化工学院西安 710021
c 上海科技大学物质科学与技术学院上海 201210

投稿日期:2022-12-23 发布日期:2023-02-16

作者简介:

殷政, 博士、副教授、硕士生导师. 2015年博士毕业于广西师范大学, 导师曾明华教授, 随后进入陕西科技大学工作. 主要从事功能配位聚合物材料的晶态、固态及玻璃态结构转变、后合成修饰及功能调变相关研究.

赵英博, 博士, 上海科技大学助理教授、研究员、博士生导师. 2017年博士毕业于加州大学伯克利分校, 导师Omar Yaghi教授. 2017至2021年在加州大学伯克利分校电子工程系从事博士后研究, 合作导师Ali Javey教授. 2021年8月加入上海科技大学. 主要开展分子框架结构设计合成、界面生长控制和功能器件构筑的相关研究.

曾明华, 博士, 广西师范大学教授、博士生导师, 国家自然科学基金杰出青年科学基金获得者(2015), 国家“万人计划”科技创新领军人才(2017). 2004年博士毕业于中山大学, 导师陈小明教授. 在功能配位化学及溶液配位领域, 系统性开展基于固-液结构关联、固-固结构对应性的配位导向序列化串联反应过程与机理、多级结构演变及其物化性能效应研究.

基金资助:
国家自然科学基金(22171075); 广西八桂英才项目(2019AC26001); 霍英东教育基金会高等院校青年教师基金(171110); 上海市科学技术委员会项目(22QC1401500); 上海市科学技术委员会项目(21DZ2260400)

Challenge, Advance and Emerging Opportunities for Metal-Organic Framework Glasses: from Dynamic Chemistry to Material Science and Noncrystalline Physics

Zheng Yin^a^,^b(), Yingbo Zhao^c(), Minghua Zeng^a()

a Chemistry and Pharmaceutical Sciences, State Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, Guangxi Normal University, Guilin 541004
b College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi’an 710021
c School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210

Received:2022-12-23 Published:2023-02-16
Contact: *E-mail: yinzheng@sust.edu.cn; zhaoyb2@shanghaitech.edu.cn; zmh@mailbox.gxnu.edu.cn
Supported by:
National Natural Science Foundation of China(22171075); BaGui Talent Program of Guangxi Province(2019AC26001); Young Teachers Grants from the Fok Ying-Tong Education Foundation(171110); Science and Technology Commission of Shanghai Municipality(22QC1401500); Science and Technology Commission of Shanghai Municipality(21DZ2260400)

文章分享

摘要/Abstract

金属有机框架(简称MOF)玻璃为传统玻璃世界和非晶物理研究带来崭新成员, 被视为下一代多孔化学及新型MOF衍生功能材料关键发展方向. 作为金属离子或簇核与有机配体通过配位键连接形成的多孔网络, 绝大多数MOF还未达到高温熔融态就不可避免地发生热分解, 很难通过传统的熔融-淬冷法制备玻璃. 面对相关挑战, 本综述系统梳理MOF玻璃发展历程及最新进展, 提出基于动态化学串联扰动的全新策略用于普适化制备MOF玻璃. 基于新的玻璃化方法, 发现更多MOF玻璃、阐明结构转变本质并拓展新颖性质功能是从动态化学到材料和非晶物理的重大学科交叉前沿. 相关研究孕育系列新机遇, 包括从框架/动态化学的设计和调控到MOF玻璃可控制备, 从晶态MOF本征性质到其玻璃态的各种潜在性能及新功能应用, 以及从MOF多物相多层次结构转换出发更好理解玻璃本质.

关键词: 金属有机框架, 玻璃化转变, 串联扰动, 动态化学, 非晶物理

The emerging metal-organic framework (MOF) glass, that is brand-new comer to the traditional glass and noncrystalline physics world, was viewed as the Holy Grail of future porous chemistry and the key direction of MOF derived functional materials. The known examples of MOF glass are extremely scarce, prepared mainly through the traditional melt-quenching method. As porous framework constructed from metal ions/clusters and organic linkers through coordinative bonds, the majority of MOFs can not reach high-temperature melt state, which prevents MOF glass formation. Facing these challenges, here we summarized the development history and latest advance of MOF glass. A new strategy of sequential perturbation based on dynamic chemistry was presented to widely prepare MOF glass. How to discover more MOF glasses, expand their properties and functions, and clarify their nature, is the new interdisciplinary frontier from dynamic chemistry to material science and noncrystalline physics. This topic also provides a range of new research opportunities, including the design and regulation of MOF glass based on reticular and dynamic chemistry, exploring new functions of MOF glass beyond its crystalline counterpart, and effectively responding to the scientific challenges in noncrystalline physics including the glass nature, based on the solid-solid structure transformation and relevance between crystalline and glassy MOFs.

Key words: metal-organic framework, glass transition, sequential perturbation, dynamic chemistry, noncrystalline physics

引用此文

殷政, 赵英博, 曾明华. 动态化学与材料和非晶物理新关联——金属有机框架玻璃的挑战、进展与新机遇[J]. 化学学报, 2023, 81(3): 246-252.

Zheng Yin, Yingbo Zhao, Minghua Zeng. Challenge, Advance and Emerging Opportunities for Metal-Organic Framework Glasses: from Dynamic Chemistry to Material Science and Noncrystalline Physics[J]. Acta Chimica Sinica, 2023, 81(3): 246-252.

导出引用 EndNote|Reference Manager|ProCite|BibTeX|RefWorks

分享此文

图/表 5

图1. MOF及CP玻璃领域发展历程, 关键突破、代表性化合物、结构转变机理和相关性质与功能应用

Figure 1. The development and advance of MOF and CP glasses, including the key breakthrough, typical compounds, representative works in mechanism, properties and function study The figures (a)~(c) were reproduced from Ref. [18] with permission from Nature Publishing Group, Ref. [20] with permission from American Association for the Advancement of Science, and Ref. [35] with permission from American Chemical Society

图2. MOF及CP玻璃领域近年来文献发表情况及主要化合物类别

Figure 2. The annual statics of literatures on MOF and CP glasses and the distribution of different compound categories

MOFs	Formula	T_m/K	Vitrification	T_g/K	Glass Properties and Functions
ZIF-4	[Zn(Im)₂]	863	MQ, MM	570	Strong/fragile liquid change, fragility index of 39, E=8.2 GPa, H=0.92 GPa, solid-state electrolyte for LMB
GIS	[Zn(Im)₂]	857	MQ	564	Fragility index of 39, E=8.5 GPa, H=0.9 GPa
ZIF-62	[Zn(Im)_1.75(bIm)_0.25] [Zn(Im)_2-_x(bIm)_x] (x=0.03~0.35) [Co(Im)_1.7(bIm)_0.3] [Zn_1-_xCo_x(Im)_1.7(bIm)_0.3] (x=0.007~0.5)	708 643~721 705 672~725	MQ MQ MQ MQ	595 565~602 563 604~607	Properties for family: (i) ultrahigh glass-forming ability, fragility index of 23, viscosity of 10⁵ Pa•s at T_m, Poisson’s ratio of 0.45; mixed metal and ligand ratio modified T_m and T_g; (ii) fracture toughness of 0.1 MPa•m^0.5, anomalous brittle-to-ductile transition, creep resistance, low strain-rate sensitivity, (iii) CO₂ uptake of 0.75 mmol•g^-1(273 K, 95 kPa) for a_gZIF-62(Co), selective sorption to n-butane, propane and propylene; glass membrane for H₂/CH₄, CO₂/N₂ and CO₂/CH₄ separation; (iv) transmittance up to 90% for visible and near-infrared wave, 1.5~4.8 μm mid-infrared luminescence, strong NLO response with modulation depth of 63.85%; (v) anode with exceptional cycling-induced capacity enhancement for lithium-ion batteries, flexible electrodes for oxygen evolution reaction
ZIF-76	[Zn(Im)_1.33(5-mbIm)_0.67]	724	MQ	583	Permanent gas accessible porosity with CO₂ adsorption of 4% (w) at 273 K
ZIF-8	[Zn(mIm)₂] (Ionic liquid incorporated)	654	MQ	595	High T_g/T_m of 0.91, E=5.42 GPa, H=0.73 GPa, a four-fold increase of glass’ porosity after ionic liquid washing
Others	[Ag(pL₂)(CF₃SO₃)] [Ti₁₆O₁₆₍BPA)_x(OR)₃₂₋_x] [Co(pybz)₂]₄_n	544	MQ, MM VE SP	434 — 568	Adsorption capacity of 9.2 cm³/g (CO₂, 195 K) and 160 cm³/g (benzene vapor) 77 K N₂ accessible internal surface area of 267 m²/g Fragility index of 83, supercooled liquid range of 26 K, thermal stable for 10⁴ s at T_g, CH₃OH and CO₂ accessible porosity
		—
		—

MOFs	Formula	T_m/K	Vitrification	T_g/K	Glass Properties and Functions
ZIF-4	[Zn(Im)₂]	863	MQ, MM	570	Strong/fragile liquid change, fragility index of 39, E=8.2 GPa, H=0.92 GPa, solid-state electrolyte for LMB
GIS	[Zn(Im)₂]	857	MQ	564	Fragility index of 39, E=8.5 GPa, H=0.9 GPa
ZIF-62	[Zn(Im)_1.75(bIm)_0.25] [Zn(Im)_2-_x(bIm)_x] (x=0.03~0.35) [Co(Im)_1.7(bIm)_0.3] [Zn_1-_xCo_x(Im)_1.7(bIm)_0.3] (x=0.007~0.5)	708 643~721 705 672~725	MQ MQ MQ MQ	595 565~602 563 604~607	Properties for family: (i) ultrahigh glass-forming ability, fragility index of 23, viscosity of 10⁵ Pa•s at T_m, Poisson’s ratio of 0.45; mixed metal and ligand ratio modified T_m and T_g; (ii) fracture toughness of 0.1 MPa•m^0.5, anomalous brittle-to-ductile transition, creep resistance, low strain-rate sensitivity, (iii) CO₂ uptake of 0.75 mmol•g^-1(273 K, 95 kPa) for a_gZIF-62(Co), selective sorption to n-butane, propane and propylene; glass membrane for H₂/CH₄, CO₂/N₂ and CO₂/CH₄ separation; (iv) transmittance up to 90% for visible and near-infrared wave, 1.5~4.8 μm mid-infrared luminescence, strong NLO response with modulation depth of 63.85%; (v) anode with exceptional cycling-induced capacity enhancement for lithium-ion batteries, flexible electrodes for oxygen evolution reaction
ZIF-76	[Zn(Im)_1.33(5-mbIm)_0.67]	724	MQ	583	Permanent gas accessible porosity with CO₂ adsorption of 4% (w) at 273 K
ZIF-8	[Zn(mIm)₂] (Ionic liquid incorporated)	654	MQ	595	High T_g/T_m of 0.91, E=5.42 GPa, H=0.73 GPa, a four-fold increase of glass’ porosity after ionic liquid washing
Others	[Ag(pL₂)(CF₃SO₃)] [Ti₁₆O₁₆₍BPA)_x(OR)₃₂₋_x] [Co(pybz)₂]₄_n	544	MQ, MM VE SP	434 — 568	Adsorption capacity of 9.2 cm³/g (CO₂, 195 K) and 160 cm³/g (benzene vapor) 77 K N₂ accessible internal surface area of 267 m²/g Fragility index of 83, supercooled liquid range of 26 K, thermal stable for 10⁴ s at T_g, CH₃OH and CO₂ accessible porosity
		—
		—

表1. 典型MOF玻璃的制备方法(MQ为熔融-淬冷, MM为机械研磨, VE为溶剂挥发, SP为串联扰动)、热力学参数、性质及功能应用

Table 1. Summary of the vitrification methods (melting-quenching, MQ; mechanic-milling, MM; vapor evaporation, VE; sequential perturbation, SP), thermal parameters, properties and function of selected typical MOF glasses

表1. 典型MOF玻璃的制备方法(MQ为熔融-淬冷, MM为机械研磨, VE为溶剂挥发, SP为串联扰动)、热力学参数、性质及功能应用

图3. (a)晶态与玻璃态物质能量分布对比图. (b) MOF的内在动态化学特征. (c)金属节点配位插入及去除实现串联扰动示意图

Figure 3. (a) Comparison of the energy state of crystal and glass. (b) Illustration of the inherent dynamics of MOF. (c) Schematic diagram of perturbation at the metal node through coordinative insertion and removing M, L1 and L2 represent the metal ion, potential leaving ligand and attacking ligand. The brown shadow indicates the vertical view of the coordination polyhedron. The figure was reproduced from Ref. [35] with permission from American Chemical Society

图4. (a)传统熔融-淬冷法及(b)串联扰动法制备玻璃热力学路径对比

Figure 4. The thermodynamic routes to prepare MOF glass through (a) traditional melt-quenching method and (b) sequential perturbation approach

参考文献 55

[1]	Special issue for Science's ¹²⁵th anniversary. Science 2005, 309, 78.
[2]	Wang W. H. Prog. Phys. 2013, 33, 177. (in Chinese)
	(汪卫华, 物理学进展, 2013, 33, 177.)
[3]	Zhang Q. Y.; Wang W. C.; Jiang Z. H. Chin. Sci. Bull. 2016, 13, 1407. (in Chinese)
	(张勤远, 王伟超, 姜中宏, 科学通报, 2016, 13, 1407.)
[4]	Debenedetti P. G.; Stillinger F. H. Nature 2001, 410, 259. doi: 10.1038/35065704
[5]	Li M. X.; Liu Y. H.; Wang W. H.; Zhao S. F.; Lu Z.; Hirata A.; Wen P.; Bai H. Y.; Chen M.; Schroers J. Nature 2019, 569, 99. doi: 10.1038/s41586-019-1145-z
[6]	Zachariasen W. H. J. Am. Chem. Soc. 1932, 54, 3841. doi: 10.1021/ja01349a006
[7]	Flory P. J. J. Chem. Phys. 1949, 17, 303. doi: 10.1063/1.1747243
[8]	Bernal J. D. Nature 1960, 185, 68. doi: 10.1038/185068a0
[9]	Chen X. M.; Zhang J. P. Metal-Organic Framework Materials, Chemical Industry Press, Beijing, 2017. (in Chinese)
	(陈小明, 张杰鹏, 金属-有机框架材料, 化学工业出版社, 北京, 2017.)
[10]	Furukawa H.; Cordova K. E.; O'Keeffe M.; Yaghi O. M. Science 2013, 341, 974.
[11]	Kitagawa S. Acc. Chem. Res. 2017, 50, 514. doi: 10.1021/acs.accounts.6b00500
[12]	Bennett T. D.; Goodwin A. L.; Dove M. T.; Keen D. A.; Tucker M. G.; Barney E. R.; Soper A. K.; Bithell E. G.; Tan J. C.; Cheetham A. K. Phys. Rev. Lett. 2010, 104, 115503. doi: 10.1103/PhysRevLett.104.115503
[13]	Bennett T. D.; Yue Y.; Li P.; Qiao A.; Tao H.; Greaves N. G.; Richards T.; Lampronti G. I.; Redfern S. A. T.; Blanc F.; Farha O. K.; Hupp J. T.; Cheetharm A. K.; Keen D. A. J. Am. Chem. Soc. 2016, 138, 3484. doi: 10.1021/jacs.5b13220 pmid: 26885940
[14]	Gaillac R.; Pullumbi P.; Beyer K. A.; Chapman K. W.; Keen D. A.; Bennett T. D.; Coudert F. X. Nat. Mater. 2017, 16, 1149. doi: 10.1038/nmat4998 pmid: 29035353
[15]	Widmer R. N.; Lampronti G. I.; Anzellini S.; Gaillac R.; Farsang S.; Zhou C.; Belenguer A. M.; Wilson C. W.; Palmer H.; Kleppe A. K.; Wharmby M. T.; Yu X.; Cohen S. M.; Telfer S. G.; Redfern S. A. T.; Coudert F. X.; MacLeod S. G.; Bennett T. D. Nat. Mater. 2019, 18, 370. doi: 10.1038/s41563-019-0317-4 pmid: 30886398
[16]	Longley L.; Calahoo C.; Limbach R.; Xia Y.; Tuffnell J. M.; Sapnik A. F.; Thorne M. F.; Keeble D. S.; Keen D. A.; Wondraczek L.; Bennett T. D. Nat. Commun. 2020, 11, 5800. doi: 10.1038/s41467-020-19598-9 pmid: 33199681
[17]	Shaw B. K.; Hughes A. R.; Ducamp M.; Moss S.; Debnath A.; Sapnik A. F.; Thorne M. F.; McHugh L. N.; Pugliese A.; Keeble D. S.; Chater P.; Bermudez-Garcia J. M.; Moya X.; Saha S. K.; Keen D. A.; Coudert F.-X.; Blanc F.; Bennett T. D. Nat. Chem. 2021, 13, 778. doi: 10.1038/s41557-021-00681-7
[18]	Bennett T. D.; Tan J. C.; Yue Y. Z.; Baxter E.; Ducati C.; Terrill N. J.; Yeung H. H. M.; Zhou Z. F.; Chen W. L.; Henke S.; Cheetham A. K.; Greaves G. N. Nat. Commun. 2015, 6, 8079. doi: 10.1038/ncomms9079 pmid: 26314784
[19]	Greaves G. N. In Springer Handbook of Glass, Eds.: Musgraves, J. D.; Hu, J.; Calvez, L., Springer International Publishing, Cham, 2019, pp. 719-770.
[20]	Qiao A.; Bennett T. D.; Tao H. Z.; Krajnc A.; Mali G.; Doherty C. M.; Thornton A. W.; Mauro J. C.; Greaves G. N.; Yue Y. Z. Sci. Adv. 2018, 4, 6827. doi: 10.1126/sciadv.aao6827 pmid: 29536040
[21]	Zheng Q.; Zhang Y.; Montazerian M.; Gulbiten O.; Mauro J. C.; Zanotto E. D.; Yue Y. Chem. Rev. 2019, 119, 7848. doi: 10.1021/acs.chemrev.8b00510
[22]	Madsen R. S. K.; Qiao A.; Sen J.; Hung I.; Chen K.; Gan Z.; Sen S.; Yue Y. Science 2020, 367, 1473. doi: 10.1126/science.aaz0251
[23]	Yan J.; Gao C.; Qi S.; Jiang Z.; Jensen L. R.; Zhan H.; Zhang Y.; Yue Y. Nano Energy 2022, 103, 107779. doi: 10.1016/j.nanoen.2022.107779
[24]	Gao C.; Jiang Z.; Qi S.; Wang P.; Jensen L. R.; Johansen M.; Christensen C. K.; Zhang Y.; Ravnsbaek D. B.; Yue Y. Adv. Mater. 2022, 34, 2110048. doi: 10.1002/adma.v34.10
[25]	Horike S.; Umeyama D.; Inukai M.; Itakura T.; Kitagawa S. J. Am. Chem. Soc. 2012, 134, 7612. doi: 10.1021/ja301875x
[26]	Umeyama D.; Horike S.; Inukai M.; Itakura T.; Kitagawa S. J. Am. Chem. Soc. 2015, 137, 864. doi: 10.1021/ja511019u pmid: 25530162
[27]	Ogawa T.; Takahashi K.; Kurihara T.; Nagarkar S. S.; Ohara K.; Nishiyama Y.; Horike S. Chem. Mater. 2022, 34, 5832. doi: 10.1021/acs.chemmater.2c00494
[28]	Zhao Y. B.; Lee S. Y.; Becknell N.; Yaghi O. M.; Angell C. A. J. Am. Chem. Soc. 2016, 138, 10818. doi: 10.1021/jacs.6b07078
[29]	Hou J.; Chen P.; Shukla A.; Krajnc A.; Wang T.; Li X.; Doasa R.; Tizei L. H. G.; Chan B.; Johnstone D. N.; Lin R.; Schulli T. U.; Martens I.; Appadoo D.; Ari M. S.; Wang Z.; Wei T.; Lo S.-C.; Lu M.; Li S.; Namdas E. B.; Mali G.; Cheetham A. K.; Collins S. M.; Chen V.; Wang L.; Bennett T. D. Science 2021, 374, 621. doi: 10.1126/science.abf4460
[30]	Lin R.; Li X.; Krajnc A.; Li Z.; Li M.; Wang W.; Zhuang L.; Smart S.; Zhu Z.; Appadoo D.; Harmer J. R.; Wang Z.; Buzanich A. G.; Beyer S.; Wang L.; Mali G.; Bennett T. D.; Chen V.; Hou J. Angew. Chem. Int. Ed. 2022, 61, e202112880.
[31]	Ali M. A.; Ren J.; Zhao T.; Liu X.; Hua Y.; Yue Y.; Qiu J. ACS Omega 2019, 4, 12081. doi: 10.1021/acsomega.9b01559
[32]	Ali M. A.; Liu X.; Li Y.; Ren J.; Qiu J. Inorg. Chem. 2020, 59, 8380. doi: 10.1021/acs.inorgchem.0c00806
[33]	Sun K.; Tan D.; Fang X.; Xia X.; Lin D.; Song J.; Lin Y.; Liu Z.; Gu M.; Yue Y.; Qiu J. Science 2022, 375, 307. doi: 10.1126/science.abj2691 pmid: 35050658
[34]	Yin Z.; Zhang Y.-B.; Yu H.-B.; Zeng M.-H. Sci. Bull. 2020, 65, 1432. doi: 10.1016/j.scib.2020.05.003
[35]	Yin Z.; Zhao Y.; Wan S.; Yang J.; Shi Z.; Peng S.-X.; Chen M.-Z.; Xie T.-Y.; Zeng T.-W.; Yamamuro O.; Nirei M.; Akiba H.; Zhang Y.-B.; Yu H.-B.; Zeng M.-H. J. Am. Chem. Soc. 2022, 144, 13021. doi: 10.1021/jacs.2c04532
[36]	Peng S.-X.; Yin Z.; Zhang T.; Yang Q.; Yu H.-B.; Zeng M.-H. J. Chem. Phys. 2022, 157, 104501. doi: 10.1063/5.0109885
[37]	Ma N.; Horike S. Chem. Rev. 2022, 122, 4163. doi: 10.1021/acs.chemrev.1c00826
[38]	Nozari V.; Calahoo C.; Tuffnell J. M.; Keen D. A.; Bennett T. D.; Wondraczek L. Nat. Commun. 2021, 12, 5703. doi: 10.1038/s41467-021-25970-0 pmid: 34588462
[39]	Thorne M. F.; Gomez M. L. R.; Bumstead A. M.; Li S.; Bennett T. D. Green Chem. 2020, 22, 2505. doi: 10.1039/D0GC00546K
[40]	Li S.; Limbach R.; Longley L.; Shirzadi A. A.; Walmsley J. C.; Johnstone D. N.; Midgley P. A.; Wondraczek L.; Bennett T. D. J. Am. Chem. Soc. 2019, 141, 1027. doi: 10.1021/jacs.8b11357
[41]	To T.; Sorensen S. S.; Stepniewska M.; Qiao A.; Jensen L. R.; Bauchy M.; Yue Y.; Smedskjaer M. M. Nat. Commun. 2020, 11, 2593. doi: 10.1038/s41467-020-16382-7
[42]	Widmer R. N.; Bumstead A. M.; Jain M.; Bennett T. D.; Michler J. J. Am. Chem. Soc. 2021, 143, 20717. doi: 10.1021/jacs.1c08368 pmid: 34854678
[43]	Zhou C.; Longley L.; Krajnc A.; Smales G. J.; Qiao A.; Erucar I.; Doherty C. M.; Thornton A. W.; Hill A. J.; Ashling C. W.; Qazvini O. T.; Lee S. J.; Chater P. A.; Terrill N. J.; Smith A. J.; Yue Y.; Mali G.; Keen D. A.; Telfer S. G.; Bennett T. D. Nat. Commun. 2018, 9, 5042. doi: 10.1038/s41467-018-07532-z
[44]	Frentzel-Beyme L.; Kloss M.; Pallach R.; Salamon S.; Moldenhauer H.; Landers J.; Wende H.; Debus J.; Henke S. J. Mater. Chem. A 2019, 7, 985. doi: 10.1039/c8ta08016j
[45]	Frentzel-Beyme L.; Kloss M.; Kolodzeiski P.; Pallach R.; Henke S. J. Am. Chem. Soc. 2019, 141, 12362. doi: 10.1021/jacs.9b05558 pmid: 31288513
[46]	Wang Y.; Fin H.; Ma Q.; Mo K.; Mao H.; Feldhoff A.; Cao X.; Li Y.; Pan F.; Jiang Z. Angew. Chem. Int. Ed. 2020, 59, 4365. doi: 10.1002/anie.v59.11
[47]	Jiang G.; Qu C.; Xu F.; Zhang E.; Lu Q.; Cai X.; Hausdorf S.; Wang H.; Kaskel S. Adv. Funct. Mater. 2021, 31, 2104300. doi: 10.1002/adfm.v31.43
[48]	Zeng M. H.; Feng X. L.; Chen X. M. Dalton Trans. 2004, 2217.
[49]	Zeng M. H.; Wang Q. X.; Tan Y. X.; Hu S.; Zhao H. X.; Long L. S.; Kurmoo M. J. Am. Chem. Soc. 2010, 132, 2561. doi: 10.1021/ja908293n
[50]	Yin Z.; Wang Q. X.; Zeng M. H. J. Am. Chem. Soc. 2012, 134, 4857. doi: 10.1021/ja211381e
[51]	Zeng M. H.; Yin Z.; Tan Y. X.; Zhang W. X.; He Y. P.; Kurmoo M. J. Am. Chem. Soc. 2014, 136, 4680. doi: 10.1021/ja500191r
[52]	Yin Z.; Wan S.; Yang J.; Kurmoo M.; Zeng M. H. Coord. Chem. Rev. 2019, 378, 500. doi: 10.1016/j.ccr.2017.11.015
[53]	Zeng M.-H.; Tan Y.-X.; He Y.-P.; Yin Z.; Chen Q.; Kurmoo M. Inorg. Chem. 2013, 52, 2353. doi: 10.1021/ic301857h
[54]	Shekhah O.; Liu J.; Fischer R. A.; Woll C. Chem. Soc. Rev. 2011, 40, 1081. doi: 10.1039/c0cs00147c pmid: 21225034
[55]	Xu R. R.; Yu J. H.; Yan W. F. Prog. Chem. 2020, 32, 1017. (in Chinese)
	(徐如人, 于吉红, 闫文付, 化学进展, 2020, 32, 1017.) doi: 10.7536/PC200428

动态化学与材料和非晶物理新关联——金属有机框架玻璃的挑战、进展与新机遇

Challenge, Advance and Emerging Opportunities for Metal-Organic Framework Glasses: from Dynamic Chemistry to Material Science and Noncrystalline Physics

RichHTML

PDF

可视化

摘要/Abstract

引用此文

分享此文

图/表 5

参考文献 55

相关文章 15

编辑推荐

相关统计

本文评价

[1]	刘洋, 高丰琴, 马占营, 张引莉, 李午戊, 侯磊, 张小娟, 王尧宇. 一例钴基金属有机框架化合物活化过氧单硫酸盐高效降解水中亚甲基蓝研究[J]. 化学学报, 2024, 82(2): 152-159.
[2]	孙博, 琚雯雯, 王涛, 孙晓军, 赵婷, 卢晓梅, 陆峰, 范曲立. 高分散共轭聚合物-金属有机框架纳米立方体的制备及抗肿瘤应用[J]. 化学学报, 2023, 81(7): 757-762.
[3]	齐学平, 王飞, 张健. 后合成法构筑钛基金属有机框架及其应用[J]. 化学学报, 2023, 81(5): 548-558.
[4]	陈俊畅, 张明星, 王殳凹. 晶态多孔材料合成方法的研究进展[J]. 化学学报, 2023, 81(2): 146-157.
[5]	程敏, 王诗慧, 罗磊, 周利, 毕可鑫, 戴一阳, 吉旭. 面向乙烷/乙烯分离的金属有机框架膜的大规模计算筛选[J]. 化学学报, 2022, 80(9): 1277-1288.
[6]	闫绍兵, 焦龙, 何传新, 江海龙. ZIF-67/石墨烯复合物衍生的氮掺杂碳限域Co纳米颗粒用于高效电催化氧还原[J]. 化学学报, 2022, 80(8): 1084-1090.
[7]	闫续, 屈贺幂, 常烨, 段学欣. 金属有机框架在气体预富集、预分离及检测中的应用[J]. 化学学报, 2022, 80(8): 1183-1202.
[8]	何家伟, 焦柳, 程雪怡, 陈光海, 吴强, 王喜章, 杨立军, 胡征. 金属有机框架衍生的空心碳纳米笼的结构调控与锂硫电池性能研究[J]. 化学学报, 2022, 80(7): 896-902.
[9]	曹琳安, 魏敏. 电子导电金属有机框架薄膜的研究进展[J]. 化学学报, 2022, 80(7): 1042-1056.
[10]	谢晨帆, 徐玉平, 高明亮, 徐忠宁, 江海龙. MOF基Pd单位点催化CO酯化制碳酸二甲酯[J]. 化学学报, 2022, 80(7): 867-873.
[11]	耿元昊, 林小秋, 孙亚昕, 李惠雨, 秦悦, 李从举. 双金属导电金属有机框架材料Ni/Co-CAT的制备及其氧还原催化性能研究[J]. 化学学报, 2022, 80(6): 748-755.
[12]	王诗慧, 薛小雨, 程敏, 陈少臣, 刘冲, 周利, 毕可鑫, 吉旭. 机器学习与分子模拟协同的CH₄/H₂分离金属有机框架高通量计算筛选[J]. 化学学报, 2022, 80(5): 614-624.
[13]	张容, 柳江萍, 朱子怡, 陈淑妹, 王飞, 张健. 二茂铁功能化的两例镉金属有机框架材料的合成、结构和表征^※[J]. 化学学报, 2022, 80(3): 249-254.
[14]	朱鹏飞, 娄晨思, 史雨翰, 王传义. Ag/AgCl/ZIF-8复合材料的制备及其对NO光催化氧化性能的研究[J]. 化学学报, 2022, 80(10): 1385-1393.
[15]	郝肖柯, 翟振宇, 孙亚昕, 李从举. 柔性可水洗的Zr-MOFs复合纳米纤维薄膜的制备和性能表征[J]. 化学学报, 2022, 80(1): 49-55.