SIOC English
化学学报
高级检索

化学学报 ›› 1999, Vol. 57 ›› Issue (7): 820-830. 上一篇    下一篇

研究论文

β-烷氧羰乙基三氯化锡与Schiff碱配合物的合成、表征与结构

李忠芳;傅芳信;潘华德;邢彦;林永华   

  1. 山东工程学院科技研究院;东北师范大学化学系.长春(130024);中国科学院长 春应用化学研究所.长春(130022)
  • 发布日期:1999-07-15

Synthesis,structure charaterization of the complexes of β- alkoxycarbonylethyltin trichlorides with schiff base ligands

Li Zhongfang;Fu Fangxin;Pan Huade;Xing Yan;Lin Yonghua   

  1. NE Normal Univ, Dept Chem.Changchun(130024);Changchun Inst Appl Chem. , CAS.Changchun(130022)
  • Published:1999-07-15

PDF

269

被引次数

38

合成表征了32个标题化合物ROCOCHR^1CH~2SnCl~3.(2-HOC~6H~4CH==NC~6H~4-X)(R=Me,Et,n-Bu;R^1=H,Me;X=H,4'-Cl,3'-Br,3'-OH,3',4'-Cl~2,4'-OMe),通过元素分析,UV-vis,IR和^1HNMR进行了表征.n-BuOCOCH~2CH~2SnCl~3.(2-HOC~6H~4CH==NC~6H~4OMe-4')的晶体结构分析表,该晶体属单斜晶系,a=1.4661(3)nm,b=0.9307(2)nm,c=1.7888(4)nm,β=94.04(3)^o;v=2.4348nm^3,z=4;空间群P2~1/c.该化合物为含有分子内羰基氧配位,Schiff碱以酚羟基上的氧原子配位,中心锡原子为六配位,空间构型为畸变八面体构型的单分子有机锡化合物。

关键词: 席夫碱, 锡络合物, 晶体结构, 烷氧羰基, 元素分析, 紫外分光光度法, 红外分光光度法, 质子磁共振谱法

Thirty -two title complexes ROCOCHR^1CH~2SnCl~3.(2-HOC~6H~4CH= =NC~6H~4-X)(R=Me,Et, n-Bu;R^1=H,Me;X=H,4'-Cl,3'-Br,3'-OH,3',4'-Cl~2,4'- OMe), were synthesized and characterized by elemental analysis, UV-vis, IR,^1H NMR. The crystal structure of n-BuOCOCH~2CH~2SnCl~3.(2- HOC~6H~4CH= =NC~6H~4OMe-4') were determined by the X-ray diffraction analysis. The crystal belongs to monoclinic system, with a=1.4661(3) nm,b=0.9307(2)nm, c=1.7888(4)nm,β=94.04(3)^o;v=2.4348nm^3, D~c=1. 581mg/m^3, z=4,F(000) =1160,μ=1.405mm^-^1,R=0.0354,R~w=0.0486.space group:P2~1/c. The complexes exist as a discrete monomer. The tin atom has a distorted octahedral geometry due to intramolecular coordination of the carbonyl oxygen and the phenolic oxygen of the Schiff base ligands. The coordination number of tin atom is 6.

Key words: SCHIFF BASE, TIN COMPLEX, CRYSTAL STRUCTURE, ALKOXYCARBONYL GROUP, ELEMENTAL ANALYSIS, ULTRAVIOLET SPECTROPHOTOMETRY, INFRARED SPECTROPHOTOMETRY, PROTON MAGNETIC RESONANCE SPECTROMETRY

中图分类号: