化学学报 ›› 1989, Vol. 47 ›› Issue (10): 1017-1021. 上一篇    下一篇

研究论文

甾体植物生长促进剂的研究 IX:22R-和22S-24, 25, 26, 27, 28-五失碳油菜甾醇内酯的合成

田伟生;周维善;姜标;潘鑫复   

  1. 中国科学院上海有机化学研究所;兰州大学化学系
  • 发布日期:1989-10-15

Studies on steroidal plant-growth regulator IX: THE preparation of 22R- and 22S-24, 25, 26, 27, 28-penta-nor-brassinolides

TIAN WEISHENG;ZHOU WEISHAN;JIANG BIAO;PAN XINFU   

  • Published:1989-10-15

从猪去氧胆酸合成了两个新的油菜甾醇内酯类似物2和3, 它们的22-碳构型经其钼配合物的CD测定分别确定为R和S。

关键词: 内酯, 甾族化合物, 甾醇, 生长素, 圆振二向色性, 植物生长调节剂, 消旋体拆分, 构型, 胆甾烷类, 猪去氧胆酸

The title compounds I were prepared in several steps starting from hyodeoxycholic acid.

Key words: LACTONES, STEROIDS, STEROL, AUXIN, CIRCULAR DICHROISM, PLANT GROWTH REGULATORS, MESOTOMY, CONFIGURATION, CHOLESTANES, HYODEOXYCHOLIC ACID

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