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化学学报
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化学学报 ›› 2010, Vol. 68 ›› Issue (05): 374-378. 上一篇    下一篇

研究论文

层状二氧化锰和2,2-联吡啶铁自组装膜的制备和光电性能研究

于书平，席铭俊，韩克飞，汪中明，朱红   

  1. (北京化工大学化工资源有效利用国家重点实验室 北京 100029)
  • 投稿日期:2009-07-23 修回日期:2009-10-22 发布日期:2010-03-14
  • 通讯作者: 朱红 E-mail:zhu_ho@126.com
  • 基金资助:

    国家自然科学基金(No. 20876013)

Preparation and Photoelectric Properties of Layered Manganese Oxide/2,2-bipyridine Iron Self-assembled Film

Yu Shuping Xi Mingjun Han Kefei Wang Zhongming Zhu Hong   

  1. (State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029)
  • Received:2009-07-23 Revised:2009-10-22 Published:2010-03-14
  • Contact: Shu-Ping YU E-mail:zhu_ho@126.com

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2008

被引次数

5 | 1

采用静电吸附层-层自组装方法制备了层状二氧化锰/2,2-联吡啶铁自组装膜材料, 借助扫描电镜(SEM), 紫外可见光谱(UV-Vis)和电化学工作站等测试手段对自组装膜的结构与性能进行了表征. 结果表明, 该自组装膜具有均匀的表面和紧密的层状结构, 在可见光照射条件下该自组装膜电极的氧化还原电流明显增加了. 层状二氧化锰/2,2-联吡啶铁自组装膜电极, 在可见光照射条件下光电降解有机染料罗丹明B (1×10－5 mol/L)反应80 min降解率达到了57%.

关键词: 层状二氧化锰, 2,2-联吡啶铁, 光电催化, 自组装膜, 罗丹明B

The layered manganese oxide (MnO2)/2,2-bipyridine iron [Fe(bipy)] composite was synthesized by an electrostatic adsorption layer-by-layer self-assembly technique, and characterized by scanning electron microscopy (SEM), ultraviolet-visible (UV-Vis) spectra and electrochemical measurements. The results showed that Fe(bipy) was uniformly deposited by the layer-by-layer adsorption technique and the photocurrent of self-assembled film was increased under visible light irradiation. This system could degrade 57% of RhB (with concentration of 1×10－5 mol/L) in 80 min, which could achieve a better effect of degradation in short time.

Key words: layered manganese oxide, 2,2-bipyriding iron, photoelectrocatalysis, self-assembled film, rhodamine B

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