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化学学报
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化学学报 ›› 2011, Vol. 69 ›› Issue (03): 316-324. 上一篇    下一篇

研究论文

水溶性磺酸钠苯基卟啉及其金属配合物共价与非共价修饰多壁碳纳米管的研究

张辉1，赵鸿斌*,1,2，陆旭甲1，王武林1，常慧2，王玉芳1   

  1. (1湘潭大学化学学院 环境友好化学与应用省部共建教育部重点实验室 湘潭 411105)
    (2东莞理工学院化学与环境工程学院 东莞 523808)
  • 投稿日期:2010-05-05 修回日期:2010-08-07 发布日期:2010-10-11
  • 通讯作者: 赵鸿斌 E-mail:zhaohbhanlf@163.com
  • 基金资助:

    广东省自然科学基金

Water-soluble Sulfonate Sodium Phenyl Porphyrin and Its Metal Complexes Covalently and Non-covalently Modification Multi-Walled Carbon Nanotubes

Zhang Hui1 Zhao Hongbin*,1,2 Lu Xujia 1 Wang Wulin1 Chang Hui2, Wang Yufang1   

  1. (1 Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan 411105)
    (2 College of Chemical and Environmental Engineering, Dongguan University of Technology, Dongguan 523808)
  • Received:2010-05-05 Revised:2010-08-07 Published:2010-10-11

PDF

1090

被引次数

49

合成了meso-四(4-磺酸钠苯基)卟啉及其Zn, Cu, Mn配合物, 通过共价与非共价的方法将其分别修饰到多壁碳纳米管上. 采用红外光谱对产物结构进行表征|通过透射电镜(TEM)考察了卟啉-多壁碳纳米管复合物的形貌特征|通过紫外光谱、荧光光谱对比分析了两类复合物, 发现在卟啉与多壁碳纳米管之间存在较强的电子效应, 同时发现非共价修饰的卟啉-碳纳米管复合物的荧光淬灭率更高|热重分析(TGA)表明非共价的卟啉-碳纳米管复合物中卟啉的含量比较高. 对修饰后的复合物进行了溶解性测试, 结果表明共价修饰的复合物在水中有较好的溶解性和分散性.

关键词: 水溶性卟啉, 多壁碳纳米管, 共价修饰, 非共价修饰, 复合物

meso-Tetra(4-sulfonate sodium phenyl)porphyrin and its Zn, Cu, Mn complexes were synthesized. Porphyrins-MWNTs compounds were obtained by covalently and noncovalently methods. The structures of the resultant products were characterized by FTIR and the morphology features were investigated by transmission electron microscopy (TEM). Strong electeonic effects between porphyrins and MWNTs were found from UV-vis absorption and fluorescence spectroscopy, moreover, the noncovolant functionalization provides a higher fluourescence quenching than the covalent functionalization. The thermal gravity analysis (TGA) showed that the weight percentage of the porphyrins and its metal complexes attached to MWNTs which the noncovolant functionalization is more than convalent functionalization. The solubility of new compounds was tested, and the results show that the covalently modified complexes have good solubility and dispersion.

Key words: water-soluble porphyrin, multi-walled carbon nanotube, covalently modification, noncovalently modification, composite