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化学学报
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化学学报 ›› 1982, Vol. 40 ›› Issue (10): 926-931. 上一篇    下一篇

论文

苦玄参化学成分的研究——Ⅴ.苦玄参苷元Ⅴ和Ⅵ的结构

甘立宪, 毛国清, 伍文超, 周维善   

  1. 中国科学院上海有机化学研究所
  • 投稿日期:1981-06-02 发布日期:2013-06-03
  • 通讯作者: 周维善
  • 基金资助:
    国际科学基金(International Foundation for Science)的资助(IFS Grant No.R440)

STUDIES ON THE CONSTITUENTS OF PICRIA FEL-TARRAE LOUR Ⅴ. THE STRUCTURE OF PICFELTARRAEGENINS Ⅴ AND Ⅵ

GAN LI-XIAN, MAO GUO-QING, WU WEN-CHAO, ZHOU WEI-SHAN   

  1. Shanghai Institute of Organic Chemistry, Academia Sinica
  • Received:1981-06-02 Published:2013-06-03

PDF

553

被引次数

20

木文报道苦玄参提取物中的抗肿瘤活性部分,经酸水解后又分得两个新四环三萜苷元,苦玄参苷元(picfeltarraegenin)Ⅴ和Ⅵ.根据其UV,1H NMR,13C NMR,MS数据以及化学反应,证明苦玄参苷元Ⅴ和Ⅵ分别具有5和8的结构,5的结构经苦玄参苷元Ⅰ(1)的双乙酸酯(7)氧化成6而加以确证.

The strnotnral determination of two more new tetraoyolfo triterpene aglyoones, piofeltarragenins Ⅴ(5) and Ⅵ(8), iaolated from antitnmour fraction of Pieria fel-tarrae Lour extract was reported. On the basis of their apeotrosoopio data(UV, IR, 1H NMR, 13C NMR and Ms) and chemical reaotions,the structure of piofeltarraegenin Ⅴ and Ⅵ were assigned as 5 and 8 respectively. The structure of 6 was correlated with that of piofeltarraegenin Ⅰ(1) through the chromic acid oxidation of the diaoetate 7 of compound 1 which yieldedaprodact shown to be identical with the diaoetate 6 of compound 5.