化学学报 ›› 1978, Vol. 36 ›› Issue (4): 275-282. 上一篇    下一篇

论文

氟烯的结构-特性关系 Ⅱ.某些含氟烷基取代环丙烷的核磁共振谱及质谱

计国桢, 李兴亚, 吴成九, 金香珊, 徐天霏, 章云祥, 蒋锡夔   

  1. 中国科学院上海有机化学研究所
  • 投稿日期:1978-02-20 发布日期:2013-06-03

STRUCTURE-PROPERTY RELATIONSHIP OF FLUOROOLEFINS--Ⅱ.THE NMR AND MASS SPECTRA OF MONOSUBSTITUTED FLUOROALKYLCYCLOPROP ANES.

CHI KUO-CHENG, LI HSING-YA, WU CHENG-JIU, CHIN HSING-SAN, HSU TIEN-FEI, CHANG YUN-HSIANG, JIANG HSI-KWEI   

  1. Shanghai Institute of Organic Chemistry, Academia Sinica
  • Received:1978-02-20 Published:2013-06-03

本文报导了十七个新的含氟烷基单取代环丙烷的核磁共振谱及质谱数据,着重讨论了含氟烷基对环上质子的屏蔽效应.烷基取代基中α碳(与环直接相联的碳)上的氢为氟原子取代之后,不仅使所有环上质子的化学位移向低场移动,并且使环上之顺式质子与反式质子的化学位移差Δδ减小,对应于三种类型的环丙烷.

NMR and mass spectral data of seventeen monosubstituted fluoroalkylcyclopropanes are presented; the shielding effect of the fluoroalkyl groups on the ring-protons are discussed.Fluorine substitution on the carbon a to the ring not only deshields all the ring protons, but also produces anothor interesting effect.Wheroas ordinary alkyl side-chain causes a difference in shielding on the cis and trams protons with a Δδ-value of ~0.4ppm,the Δδ-values of the above mentioned cyclopropanes a,re a function of the number of fluorine atoms substituted on the a-carbon.