The replacement reaction of trinuclear molybdenum clusters: Synthesis and crystal structure of two molybdenum clusters [Mo3S4(DTC)4(DMF))](EtOH) and [Mo3S4(DTC)4(Py)](Py)2(H2O)

Acta Chimica Sinica ›› 1989, Vol. 47 ›› Issue (2): 121-127. Previous Articles Next Articles

Original Articles

三核钼簇合物配基置换反应: 两个三核钼簇合物[Mo3S4(DTC)4(DMF)](EtOH)和[Mo3S4(DTC)4(Py)](Py)2(H2O)的合成和晶体结构研究

黄明东;卢绍芳;黄建全;黄金陵

中国科学院福建物质结构研究所;福州大学化学系

发布日期:1989-02-15

The replacement reaction of trinuclear molybdenum clusters: Synthesis and crystal structure of two molybdenum clusters [Mo3S4(DTC)4(DMF))](EtOH) and [Mo3S4(DTC)4(Py)](Py)2(H2O)

HUANG MINGDONG;LU SHAOFANG;HUANG JIANQUAN;HUANG JINLING

Published:1989-02-15

Abstract

(HDTC = Et2NCS2H) were prepared by the ligand replacement reaction. The crystal structure of the 2 clusters have been determine by x-ray diffraction method. I and II belong to space group P1, Z = 4, 2, resp. I and II are trinuclear Mo clusters with the {Mo3S44+} cluster skeleton. The influence of the Mo-Mo bond by the ligands in this kind of cluster and the regularity of ligand replacement reaction are discussed.

Key words: PYRIDINE P, ETHANOL, CRYSTAL STRUCTURE, X-RAY DIFFRACTION ANALYSIS, DMSO, MOLYBDENUM COMPLEX, EXCHANGE REACTION, SULFIDE COMPLEX, CARBAMODITHIOIC ACID P

CLC Number:

O611.662

Cite this article

HUANG MINGDONG;LU SHAOFANG;HUANG JIANQUAN;HUANG JINLING. The replacement reaction of trinuclear molybdenum clusters: Synthesis and crystal structure of two molybdenum clusters [Mo3S4(DTC)4(DMF))](EtOH) and [Mo3S4(DTC)4(Py)](Py)2(H2O)[J]. Acta Chimica Sinica, 1989, 47(2): 121-127.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Yang Liu, Fengqin Gao, Zhanying Ma, Yinli Zhang, Wuwu Li, Lei Hou, Xiaojuan Zhang, Yaoyu Wang. Co-based Metal-organic Framework for High-efficiency Degradation of Methylene Blue in Water by Peroxymonosulfate Activation [J]. Acta Chimica Sinica, 2024, 82(2): 152-159.
[2]	Tiantian Lü, Wen Ma, Dongsun Zhan, Yanmin Zou, Jilong Li, Meiling Feng, Xiaoying Huang. Two New Three-Dimensional Lanthanide Metal-organic Frameworks for the Highly Efficient Removal of Cs⁺ Ions^※ [J]. Acta Chimica Sinica, 2022, 80(5): 640-646.
[3]	Jinxu Zhao, Mingshu Zhang, Wenfa Chen, Xiaoming Jiang, Binwen Liu, Guocong Guo. KAg₃Ga₈S₁₄: An Mid- and Far-infrared Nonlinear Optical Material Exhibiting High Laser-induced Damage Threshold^※ [J]. Acta Chimica Sinica, 2022, 80(3): 259-264.
[4]	Rong Zhang, Jiangping Liu, Ziyi Zhu, Shumei Chen, Fei Wang, Jian Zhang. Synthesis, Structure and Characterization of Two Ferrocene Functionalized Cadmium Metal Organic Frameworks^※ [J]. Acta Chimica Sinica, 2022, 80(3): 249-254.
[5]	Tong Jiao, Xue-lian Xu, Lei Zhang, You-yun Weng, Yu-bing Weng, Zhi-xian Gao. Research on CuO/CeO₂-ZrO₂/SiC Monolithic Catalysts for Hydrogen Production by Methanol Steam Reforming [J]. Acta Chimica Sinica, 2021, 79(4): 513-519.
[6]	Jing Fang, Wenjuan Zhao, Minghao Zhang, Qianrong Fang. A Novel Amide-functionalized Covalent Organic Framework for Selective Dye Adsorption [J]. Acta Chimica Sinica, 2021, 79(2): 186-191.
[7]	Guopeng Xiao, Weijun Qiao, Lei Zhang, Shaojun Qing, Caishun Zhang, Zhixian Gao. Study on Hydrogen Production Catalytic Materials for Perovskite Methanol Steam Reforming [J]. Acta Chimica Sinica, 2021, 79(1): 100-107.
[8]	Fu Jingru, Ben Teng. Fabrication of a Novel Covalent Organic Framework Membrane and Its Gas Separation Performance [J]. Acta Chimica Sinica, 2020, 78(8): 805-814.
[9]	Chen Guanghui, He Yanping, Zhang Lei, Zhang Jian. Syntheses and Structural Studies of a Series of Ti₄(embonate)₆-based Complexes [J]. Acta Chimica Sinica, 2020, 78(12): 1411-1417.
[10]	Wang Zhitao, Li Hui, Yan Shichen, Fang Qianrong. Synthesis of a Two-dimensional Covalent Organic Framework with the Ability of Conducting Proton along Skeleton [J]. Acta Chimica Sinica, 2020, 78(1): 63-68.
[11]	Wang Yongsheng, Zhao Yunlu, Zhao Zhenzhen, Lan Xiaolin, Xu Jinxia Xu Weixiang, Duan Zhengkang. Study on Preparation of Cu-ZrO₂ Catalyst Coated by Nitrogen-Doped Carbon and Catalytic Dehydrogenation Performance [J]. Acta Chim. Sinica, 2019, 77(7): 661-668.
[12]	Fu Wenwen, Li Yan, Liang Changhai. Dehydrogenation Mechanism of Ethanol on Co(111) Surface: A First-principles Study [J]. Acta Chim. Sinica, 2019, 77(6): 559-568.
[13]	Liu Jiao, Sun Hailong, Yin Lu, Yuan Yaxian, Xu Minmin, Yao Jianlin. On-line Monitoring on the Micro-synthesis of α-Phenylethanol by Microfluidic Chip Combined with Surface Enhanced Raman Spectroscopy [J]. Acta Chim. Sinica, 2019, 77(3): 257-262.
[14]	Liu Yucan, Su Miaomiao, Zhang Yan, Duan Jinming, Li Wei. Influence Rule of Organic Solvents Methanol from Sample Preparation on Degradation Rate and Mechanism of Atrazine in UV-based Oxidation Processes [J]. Acta Chim. Sinica, 2019, 77(1): 72-83.
[15]	Jia Zhenlong, Tu Yunbao, Wang Jianqiang, Frenkel Anatoly I., Yang Weimin, Liu Zhongneng, Xu Zhongqianga. In situ X-ray Absorption Spectroscopy Characterization of Copper Valence State in Cu-Zn/SiO₂ Catalyst [J]. Acta Chim. Sinica, 2018, 76(8): 639-643.

三核钼簇合物配基置换反应: 两个三核钼簇合物[Mo3S4(DTC)4(DMF)](EtOH)和[Mo3S4(DTC)4(Py)](Py)2(H2O)的合成和晶体结构研究

The replacement reaction of trinuclear molybdenum clusters: Synthesis and crystal structure of two molybdenum clusters [Mo3S4(DTC)4(DMF))](EtOH) and [Mo3S4(DTC)4(Py)](Py)2(H2O)

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments