Acta Chimica Sinica ›› 2000, Vol. 58 ›› Issue (3): 356-357. Previous Articles     Next Articles

Original Articles

二氯-二[2-甲氧基-6-(2'-羟乙基亚胺基甲基)苯酚]合镉(II)的 结构再研究

崔学桂;胡清萍;胡盛志   

  1. 山东大学化学学院.济南(250100);厦门大学化学系.厦门(361005)
  • 发布日期:2000-03-15

A reinvestigation of the structure of bischlorine-bis[2-methoxyl-6- (2'-hydroxyethyl imidogen methyl) phenol] cadmium(II) complex

Cui Xuegui;Hu Qingping;Hu Shengzhi   

  1. Shandong Univ., College of Chem.Jinan(250100);Xiamen Univ, Dept Chem. Xiamen(361005)
  • Published:2000-03-15

The crystal structure of the title complex previously described as monoclinic, space group Cc is corrected to be orthorhombic, space group Fdd2 with cell parameters a=1.1661(2)nm, b=3.0956(10)nm, c=1. 5475(3)nm, V=5.586(2)nm^3, Z=8. Corrections involve changing its crystal system and class as well as the lattice type, but the structure still belongs to one of the non-centrosymmetric space groups, which is necessary for the potential non-linear optical materials. Average atomic coordinates and selected bond lengths and angles are given.

Key words: PHENOL P, CADMIUM COMPLEX, METHOXY GROUP, CRYSTAL STRUCTURE, SPACE GROUPS

CLC Number: