Synthesis of Three Novel C60 Derivatives and Their Photovoltaic Cell Performance

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (1): 88-94. Previous Articles Next Articles

新型C₆₀衍生物的合成及其太阳能电池性能

郑立平¹, 周清梅¹, 王飞¹, 邓先宇¹, 俞刚¹, 曹镛¹, 宁滨², 郭志新²

1. 华南理工大学聚合物材料与器件研究所, 广州, 510640;
2. 中国科学院化学研究所, 北京, 100080

投稿日期:2003-04-02 修回日期:2003-09-24 发布日期:2014-01-26
通讯作者: 曹镛 E-mail::E-mail:poycao@scut.edu.cn
基金资助:
国家自然科学基金(No.50028302)及科技部973(No.2002CB613404)资助项目.

Synthesis of Three Novel C₆₀ Derivatives and Their Photovoltaic Cell Performance

ZHENG Li-Ping¹, ZHOU Qing-Mei¹, WANG Fei¹, DENG Xian-Yu¹, YU Gang¹, CAO Yong¹, NING Bin², GUO Zhi-Xin ²

1. Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Guangzhou 510640;
2. Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080

Received:2003-04-02 Revised:2003-09-24 Published:2014-01-26

Abstract

Three different synthetic routes were used to synthesize different C 60 derivatives: azoalkane cycloaddition, Bingle-Hirsch reaction and Prato reaction. With different chemical structures, these three compounds have different acceptor strengths. These C 60 derivatives together with -phenyl C61-butyric acid methyl ester (PCBM) were used for fabrication of solar cells in blend with poly(2-methoxy-5-(2′-ethylhexoxy)-p-phenylene)(MEH-PPV). It was shown that photovoltaic cell performance varies with acceptor structure and the solubility of the C 60 derivatives in organic solvent. Energy conversion efficiency of one of the synthesized methanofullerene-phenyl C 61-butyric acid butyl ester (PCBB), shows better performance than that of PCBM.

Key words: photovoltaic cell, conjugated polymer, fullerene

Cite this article

ZHENG Li-Ping, ZHOU Qing-Mei, WANG Fei, DENG Xian-Yu, YU Gang, CAO Yong, NING Bin, GUO Zhi-Xin . Synthesis of Three Novel C₆₀ Derivatives and Their Photovoltaic Cell Performance[J]. Acta Chimica Sinica, 2004, 62(1): 88-94.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

References

[1] Gebeyehu, D.; Brabec, C. J.; Padinger, F.; Fromherz, T.; Hummelen, J. C.; Badt, D.; Schindler, H.; Sariciftci, N. S. Synth. Met. 2001, 118, 1.
[2] Sacricitfi, N. S.; Smilowits, L.; Heeger, A. J.; Wudl, F. Science 1992, 258, 1417.
[3] Brabec, C. J.; Cravino, A.; Meissner, D.; Sariciftci, N. S.; Fromherz, T.; Rispens, M. T.; Sanchez, L.; Hummelen, J. C. Adv. Funct. Mater. 2001, 11, 374.
[4] Yu, G.; Gao, J.; Hummelen, J. C.; Wudl, F.; Heeger, A. J. Science 1995, 270, 1789.
[5] Yu, G.; Pakbaz, K.; Heeger, A. J. Appl. Phys. Lett. 1994, 64, 3422.
[6] Dyakonov, V. Physica E 2002, 14(1-2), 53.
[7] Shaheen, S. E.; Brabec, C. J.; Padinger, F.; Fromherz, T.; Hummelen, J. C.; Sariciftci, N. S. Appl. Phys. Lett. 2001, 78, 841.
[8] Brabec, C. J.; Cravino, A.; Meissner, D.; Sariciftci, N. S.; Fromherz, T.; Rispens, M. T.; Sanchez, L.; Hummelen, J. C. Adv. Funct. Mater. 2001, 11, 374.
[9] Cravino, A.; Sariciftci, N. S. J. Mater. Chem. 2002, 12(7), 1931.
[10] Wudl, F. J. Mater. Chem. 2002, 12, 1959.
[11] Hummelen, J. C.; Knight, B. W.; LePeq, F.; Wudle, F. J. Org. Chem. 1995, 60, 523.
[12] Camps, X.; Hirsch, A. J. Chem. Soc., Perkin Trans. 1 1997, 1595.
[13] Prato, M.; Maggini, M.; Giacometti, C.; Scorrano, G.; Sandona, G.; Farnia, G. Tetrahedron 1996, 52(14), 5221.
[14] Haddon, R. C. Science 1993, 261, 1545.
[15] Suzuki, T.; Maruyama, Y.; Akasaka, T.; Ando, W.; Kobayashi, K.; Nagase, S. J. Am. Chem. Soc. 1994, 116, 1359.
[16] Janssen, R. A. J.; Hummelen, J. C.; Wudle, F. J. Am. Chem. Soc. 1995, 117, 544.
[17] Maggini, M.; Scorrano, G. J. Am. Chem. Soc. 1993, 115, 9798.
[18] Deng, X.-Y.; Zheng, L.-P.; Mo, Y.-Q.; Yu, G.; Yang, W.; Weng, W.-H.; Cao, Y. Chin. J. Polym. Sci. 2001, 19, 567.
[19] Mo, Y.-Q.; Huang, J.; Jiang, J.-X.; Deng, X.-Y.; Niu, Y.-H.; Cao, Y. Chin. J. Polym. Sci. 2002, 20(5), 461.

新型C₆₀衍生物的合成及其太阳能电池性能

Synthesis of Three Novel C₆₀ Derivatives and Their Photovoltaic Cell Performance

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Lingxuan Jia, Zepang Zhan, Zihan He, Chong-an Di, Daoben Zhu. Advances and Perspectives on Organic Materials for Neuroelectronic Interface Devices^★ [J]. Acta Chimica Sinica, 2023, 81(9): 1175-1186.
[2]	Bo Sun, Wenwen Ju, Tao Wang, Xiaojun Sun, Ting Zhao, Xiaomei Lu, Feng Lu, Quli Fan. Preparation of Highly-dispersed Conjugated Polymer-Metal Organic Framework Nanocubes for Antitumor Application [J]. Acta Chimica Sinica, 2023, 81(7): 757-762.
[3]	Liu Zhenyu, Gan Li-Hua. Molecular Dynamics Simulation of Acetylene Pyrolysis into Fullerenes [J]. Acta Chimica Sinica, 2023, 81(5): 502-510.
[4]	Yuguang Sui, Jinrong Zhou, Pan Liao, Wenjie Liang, Hai Xu. A Gaint Donor-Acceptor Molecular Switch Compound: Synthesis and Properties [J]. Acta Chimica Sinica, 2022, 80(8): 1061-1065.
[5]	Zipeng Qi, Dong Gao, Zhicheng Zhu, Zhiyuan He, Guoying Bai. Regulating Optical Properties of Water-Soluble Conjugated Polythiophene with Polyvinyl Alcohol [J]. Acta Chimica Sinica, 2022, 80(7): 921-928.
[6]	Ling Qiu, Jiayi Liang, Zhuxia Zhang, Taishan Wang. Synthesis and Characterizations of ¹⁵N Isotope Labeling Metal Nitride Clusterfullerene [J]. Acta Chimica Sinica, 2022, 80(7): 874-878.
[7]	Wenyuan Lin, Qingzhe Zhu, Yunlong Ma, Peng Wang, Shuo Wan, Qingdong Zheng. Rationally Tuning Blend Miscibility of Polymer Donor and Nonfullerene Acceptor for Constructing Efficient Organic Solar Cells^※ [J]. Acta Chimica Sinica, 2022, 80(6): 724-733.
[8]	Zhiqin Wang, Bo Xiang, Xiaoyu Huang, Guolin Lu. Effect of Phosphotungstic Acid on Self-seeding of Oligo(p-phenylenevinylene)-b-poly(2-vinylpyridine)^※ [J]. Acta Chimica Sinica, 2022, 80(3): 297-302.
[9]	Bo Wu, Chong Wang, Baolin Li, Chunru Wang. Light-driven Molecular Magnetic Switch for a Metallofullerene^※ [J]. Acta Chimica Sinica, 2022, 80(2): 101-104.
[10]	Hu Yuhui, Wu Wenlin, Yu Liyang, Luo Kaijun, Xu Xiaopeng, Li Ying, Peng Qiang. Synthesis and Photovoltaic Properties of Perylene Diimide Based Small Molecular Acceptors with a Diketopyrrolopyrrole Core [J]. Acta Chimica Sinica, 2020, 78(11): 1246-1254.
[11]	Zhang Hao, Huang Long, Li Tao, Liu Bin, Bai Zeming, Li Xiaona, Lu Dan. Quantitative Structure-property Relationship of Polyfluorene Conjugated Polymers Condensed State from Solution to Film [J]. Acta Chim. Sinica, 2019, 77(5): 397-405.
[12]	Dong Wei, Nie Mengsi, Lian Yongfu. Isolation and Electrochemical Property of Tb@C₈₂ Isomers [J]. Acta Chim. Sinica, 2017, 75(5): 453-456.
[13]	Liu Ye, Yuan Jun, Zou Yingping, Li Yongfang. Research Progress of the FuranContaining Fused Ring Conjugated Organic Molecules and Polymers [J]. Acta Chim. Sinica, 2017, 75(3): 257-270.
[14]	Liu Xingfen, Wang Yateng, Huang Yanqin, Feng Xiaomiao, Fan Quli, Huang Wei. Highly Sensitive Protein Biosensor based on a Conjugated Polymer Brush [J]. Acta Chim. Sinica, 2016, 74(8): 664-668.
[15]	Zhu Haoyun, Huang Wei, Huang Yuli, Wang Weizhi. Field Effect Transistors Characteristics Based on Blends of Si Nanowires and Poly(3-dodecylthiophene) [J]. Acta Chim. Sinica, 2016, 74(5): 429-434.

新型C60衍生物的合成及其太阳能电池性能