Preparation and Characterization of a New p-Allylcalix[4]arene-bonded Silica Gel Stationary Phase for High-Performance Liquid Chromatography

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (4): 405-409. Previous Articles Next Articles

新型杯[4]芳烃高效液相色谱固定相的制备及表征

李文智^1,2, 王霞¹, 窦建民², 马春林², 陈立仁¹, 李永民¹

1. 中国科学院兰州化学物理研究所, 兰州, 730000;
2. 聊城大学化学化工学院, 聊城, 252059

投稿日期:2003-04-02 修回日期:2003-10-08 发布日期:2014-01-26
通讯作者: 李永民,E-mail:chenlr@ns.lzb.ac.cn;Tel:0931-8278931;Fax:0931-827708. E-mail:chenlr@ns.lzb.ac.cn
基金资助:
中国科学院"百人计划"资助项目.

Preparation and Characterization of a New p-Allylcalix[4]arene-bonded Silica Gel Stationary Phase for High-Performance Liquid Chromatography

LI Wen-Zhi^1,2, WANG Xia¹, DOU Jian-Min², MA Chun-Lin², CHEN Li-Ren¹, LI Yong-Min¹

1. Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000;
2. Department of Chemistry, Liaocheng University, Liaocheng 252059

Received:2003-04-02 Revised:2003-10-08 Published:2014-01-26

Abstract

For the first time calix[4]arene tetraamide bonded stationary phase was prepared by modifying silica gel with 3-mercaptopropyltriethoxysilane and coupling with p-allylcalix[4]arene tetraamide. The separation of polycyclic aromatic hydrocarbons, positional isomers of nitroaniline, benzoic esters and phthalic esters on the new calix[4]arene bonded stationary phase was achieved with acetonitrile-water or methanol-water as mobile phase. A comparison with conventional reversed phase C 18 columns shows a predominant reversed phase character and obvious priority for separation of positional isomers. The possible separation mechanism has been investigated.

Key words: calixarene, stationary phase, HPLC

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LI Wen-Zhi, WANG Xia, DOU Jian-Min, MA Chun-Lin, CHEN Li-Ren, LI Yong-Min. Preparation and Characterization of a New p-Allylcalix[4]arene-bonded Silica Gel Stationary Phase for High-Performance Liquid Chromatography[J]. Acta Chimica Sinica, 2004, 62(4): 405-409.

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References

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新型杯[4]芳烃高效液相色谱固定相的制备及表征

Preparation and Characterization of a New p-Allylcalix[4]arene-bonded Silica Gel Stationary Phase for High-Performance Liquid Chromatography

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