Synthesis and Crystal Structure of Thiacalix[4]arene Substituted by Two Diphenylphosphinylmethoxy Groups [OCH2P(O)Ph2]

Acta Chimica Sinica ›› 2005, Vol. 63 ›› Issue (6): 519-524. Previous Articles Next Articles

Original Articles

硫杂杯[4]芳烃氧化膦衍生物的合成与晶体结构

马淑兰¹，郭倩玲²，朱文祥*^,1，赵明新¹，张静¹，刘迎春¹

(¹北京师范大学化学系北京 100875)
(²北京化工大学化学工程学院北京 100029)

投稿日期:2004-08-23 修回日期:2004-11-28 发布日期:2010-12-10
通讯作者: 朱文祥

Synthesis and Crystal Structure of Thiacalix[4]arene Substituted by Two Diphenylphosphinylmethoxy Groups [OCH₂P(O)Ph₂]

MA Shu-Lan¹, GUO Qian-Ling², ZHU Wen-Xiang*^,1, ZHAO Ming-Xin¹, ZHANG Jing¹, LIU Ying-Chun¹

(¹ Department of Chemistry, Beijing Normal University, Beijing 100875)
(² College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029)

Received:2004-08-23 Revised:2004-11-28 Published:2010-12-10
Contact: ZHU Wen-Xiang

Abstract

The lower-rim doubly substituted thiacalixarene, 5,11,17,23-tetra-tert-butyl-25,27-bis(diphenylphosphinylmethoxy)thiacalix[4]arene (compound 1), has been synthesized. The crystal structure of the compound was determined by X-ray diffraction. The result shows that the composition of compound 1 is C₆₆H₇₀O₆P₂S₄•2CH₃OH. It belongs to triclinic crystal system, space group P1, with a＝1.3453(6) nm, b＝1.5289(7), c＝1.7893(9) nm, α＝75.707(9)°, β＝69.131(8)°, γ＝79.734(9)°, Z＝2, V＝3.316(3) nm³, d＝1.215 g/cm³, F(000)＝1288, μ(Mo Kα)＝0.244 mm^－1, R₁＝0.0625, wR₂＝0.1372. The compound adopts a cone conformation.

Key words: thiacalix[4]arene, phosphinoxide, crystal structure

Cite this article

MA Shu-Lan, GUO Qian-Ling², ZHU Wen-Xiang*^,1, ZHAO Ming-Xin, ZHANG Jing, LIU Ying-Chun. Synthesis and Crystal Structure of Thiacalix[4]arene Substituted by Two Diphenylphosphinylmethoxy Groups [OCH₂P(O)Ph₂][J]. Acta Chimica Sinica, 2005, 63(6): 519-524.

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硫杂杯[4]芳烃氧化膦衍生物的合成与晶体结构

Synthesis and Crystal Structure of Thiacalix[4]arene Substituted by Two Diphenylphosphinylmethoxy Groups [OCH₂P(O)Ph₂]

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