Study on the Synthesis and Anion Recognition of Fluorescent Bi-azacrown Based on Amide

Acta Chimica Sinica ›› 2006, Vol. 64 ›› Issue (22): 2271-2274. Previous Articles Next Articles

Original Articles

基于酰胺的荧光双冠醚阴离子受体的合成和识别性能研究

秦海娟, 杨洗, 何永炳*, 卿光焱, 刘成金

(武汉大学化学系武汉 430072)

投稿日期:2005-03-10 修回日期:2006-05-31 发布日期:2006-11-28
通讯作者: 何永炳

Study on the Synthesis and Anion Recognition of Fluorescent Bi-azacrown Based on Amide

QIN Hai-Juan; YANG Xi; HE Yong-Bing*; QING Guang-Yan; LIU Cheng-Jin

(Department of Chemistry, Wuhan University, Wuhan 430072)

Received:2005-03-10 Revised:2006-05-31 Published:2006-11-28
Contact: HE Yong-Bing

Abstract

A fluorescent anion receptor (3) based on amide macrocycle was synthesized and the recognition ability for F^－, Cl^－, Br^－, I^－, H₂PO₄^－ and AcO^－ was investigated by fluorescence, UV-vis and ¹H NMR spectra. The results indicate that receptor 3 has a good selective recognition property for F^－ and formed a 1∶2 complex. The association con-stant of complex between 3 and F^－ was calculated from the changes in fluorescence intensity.

Key words: azacrown, anion receptor, fluorescence, anion recognition

Cite this article

QIN Hai-Juan; YANG Xi; HE Yong-Bing*; QING Guang-Yan; LIU Cheng-Jin. Study on the Synthesis and Anion Recognition of Fluorescent Bi-azacrown Based on Amide[J]. Acta Chimica Sinica, 2006, 64(22): 2271-2274.

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基于酰胺的荧光双冠醚阴离子受体的合成和识别性能研究

Study on the Synthesis and Anion Recognition of Fluorescent Bi-azacrown Based on Amide

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