Structural researth for mew phosphadiazine compounds

Abstract

The crystal structures of 6,12-dioxo-1-(p-chlorophenyl)imino-11-ethyl-1,4,3-thiaazaphosphacycloh exano[3,4-b]-1,3,2-benzodiazaphosphorin (I) and 6,12-dioxo-1-N-benzylideneamino-11-ethoxycarbonylmethyl-1,4,3-thiaaz aphosphacyclohexano[3,4-b]-1,3,2-benzodiazaphosphorin (II) have been determine by X-ray diffraction method. The crystals of I are monoclinic. The crystals of II are orthorhombic. The conformations of these two new phosphadiazine compounds and the factors which influence the conformations are discussed.

Key words: CRYSTAL STRUCTURE, X-RAY DIFFRACTION ANALYSIS, NITROGEN HETEROCYCLICS, PHOSPHOROUS HETEROCYCLIC COMPOUNDS, SULFUR HETEROCYCLICS COMPOUNDS, CONFORMATION, THREEMEMBER HETEROCYCLICS COMPOUNDS

CLC Number:

O619

Cite this article

CHEN RUYU;BAO RONG;YAO XINKAN;WANG RUJI. Structural researth for mew phosphadiazine compounds[J]. Acta Chimica Sinica, 1991, 49(3): 225-231.

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