Studies on synthesis and properties of transition metals with o-vanillin amino acid Schiff base complexes

Acta Chimica Sinica ›› 1995, Vol. 53 ›› Issue (5): 455-461. Previous Articles Next Articles

Original Articles

过渡金属与邻香兰素氨基酸类Schiff碱配合物合成及其性质的研究

李淑兰;王红;刘德信;崔学桂;李晓燕;杨兆荷

山东大学化学系;山东大学晶体材料研究所

发布日期:1995-05-15

Studies on synthesis and properties of transition metals with o-vanillin amino acid Schiff base complexes

LI SHULAN;WANG HONG;LIU DEXIN;CUI XUEGUI;LI XIAOYAN;YANG ZHAOHE

Published:1995-05-15

Abstract

In this paper, we synthesized four kinds of Schiff base complexes with Cu(Ⅱ). Zn(Ⅱ), Ni(Ⅱ) which derived from o-vanillin. The thermoanalysis of the complexes were studied also. Kinetic parameters were obtained from the analysis of TG, DTG curves by integral and differential methods. The possible reaction mechanisms were suggested by comparision of the kinetic parameters. The kinetic equations are otained . The mathematical expression of the kinetic compensation effect of the thermal decomposition reaction had also been obtained.

Key words: AMINO ACID, COMPLEX COMPOUNDS, TRANSITION ELEMENT, SCHIFF BASE, VANILLIN

CLC Number:

O611

Cite this article

LI SHULAN;WANG HONG;LIU DEXIN;CUI XUEGUI;LI XIAOYAN;YANG ZHAOHE. Studies on synthesis and properties of transition metals with o-vanillin amino acid Schiff base complexes[J]. Acta Chimica Sinica, 1995, 53(5): 455-461.

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过渡金属与邻香兰素氨基酸类Schiff碱配合物合成及其性质的研究

Studies on synthesis and properties of transition metals with o-vanillin amino acid Schiff base complexes

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