Cp2TiCl2 catalyzed reduction of imines by isopropyl magnesium bromide

Acta Chimica Sinica ›› 1987, Vol. 45 ›› Issue (1): 103-106. Previous Articles Next Articles

Original Articles

双环戊二烯基二氯钛催化下异丙基溴化镁对亚胺的还原反应

张永敏;江金龙

杭州大学化学系

发布日期:1987-01-15

Cp2TiCl2 catalyzed reduction of imines by isopropyl magnesium bromide

ZHANG YONGMIN;JIANG JINLONG

Published:1987-01-15

Abstract

Refluxing RCH:NR1 (R = Ph, 4-ClC6H4, 4-MeOC6H4, 4-Me2NC6H4; R1 = Ph, 4-ClC6H4, 4-BrC6H4, Bu, cyclohexyl) with Me2CHMgBr in the presence of dicyclopentadienyltitanium dichloride in Et2O gave 66-93% RCH2NHR1.

Key words: CATALYSIS, CYCLOPENTADIENE P, ISOPROPYL GROUP, BROMIDE, METALLOCENES, REDUCTION REACTION, TITANIUM COMPLEX, MAGNESIUM COMPOUNDS, IMINE, GRIGNARD REAGENT

CLC Number:

O627

Cite this article

ZHANG YONGMIN;JIANG JINLONG. Cp2TiCl2 catalyzed reduction of imines by isopropyl magnesium bromide[J]. Acta Chimica Sinica, 1987, 45(1): 103-106.

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双环戊二烯基二氯钛催化下异丙基溴化镁对亚胺的还原反应

Cp2TiCl2 catalyzed reduction of imines by isopropyl magnesium bromide

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