Synthesis of Triarylamine Dyes Containing Secondary Electron-dona- ting Groups and Application in the Dye-sensitized Solar Cells

Acta Chimica Sinica ›› 2011, Vol. 69 ›› Issue (18): 2092-2098. Previous Articles Next Articles

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含二级供电基团的三苯胺类光敏染料合成及太阳能电池中的应用

梁茂，徐英军，王旭达，刘秀杰，孙喆，薛松*

(天津理工大学化学化工学院天津 300384)

投稿日期:2010-12-09 修回日期:2011-05-11 发布日期:2011-05-30
通讯作者: 薛松 E-mail:xuesong@ustc.edu.cn
基金资助:
国家863计划;国家自然科学基金;天津市自然科学基金

Synthesis of Triarylamine Dyes Containing Secondary Electron-dona- ting Groups and Application in the Dye-sensitized Solar Cells

LIANG Mao, XU Ying-Jun, WANG Xu-Da, LIU Xiu-Jie, SUN Zhe, XUE Song

(College of Chemistry and Chemical Engineering, Tianjin University of Technology, Tianjin 300384)

Received:2010-12-09 Revised:2011-05-11 Published:2011-05-30

Two triphenylamine based dyes (XS19 and XS22) containing N,N-dimethylaniline unit as secondary electron-donating groups with different conjugated lengths were synthesized and characterized with regard to their photophysical and photoelectrochemical properties. The dyes were applied into nanocrystalline TiO₂ dye-sensitized solar cells through standard operations. It was found that, introduction of N,N-dimethylaniline unit suppressed dye aggregation and brought about superior performance over the simple triphenylamine dye in terms of power conversion efficiency. For a typical device (based on XS22) a maximum power conversion efficiency of 4.7% was obtained under simulated AM1.5 irradiation (100 mW• cm^－2) with J_SC＝9.6 mA•cm^－2, V_OC＝685 mV and FF＝0.72.

Key words: dye-sensitized solar cell, organic dyes, power conversion efficiency, electron recombination

Cite this article

LIANG Mao, XU Ying-Jun, WANG Xu-Da, LIU Xiu-Jie, SUN Zhe, XUE Song. Synthesis of Triarylamine Dyes Containing Secondary Electron-dona- ting Groups and Application in the Dye-sensitized Solar Cells[J]. Acta Chimica Sinica, 2011, 69(18): 2092-2098.

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含二级供电基团的三苯胺类光敏染料合成及太阳能电池中的应用

Synthesis of Triarylamine Dyes Containing Secondary Electron-dona- ting Groups and Application in the Dye-sensitized Solar Cells

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