Synthesis, Crystal Structure and Antibacterial Activity of A Bismuth(III) Complex [Bi2(PPA)6?(Phen)2] with Phenylacetic Acid and 1,10-Phenanthroline

doi:10.6023/A1109102

Acta Chimica Sinica ›› 2012, Vol. 0 ›› Issue (04): 519-524.DOI: 10.6023/A1109102 Previous Articles

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铋(III)苯乙酸-1,10-邻菲罗啉三元配合物[Bi₂(PPA)₆·(Phen)₂]的合成、晶体结构及抑菌活性

杨树平^a, 韩立军^b, 潘燕^c, 吴争鸣^a, 何欣然^a, 陈丽娟^a

a 淮海工学院化学工程学院连云港 222005;
b 淮海工学院数理学院连云港 222005222005;
c 北京大学医学部基础医学院药理系及国家天然仿生药物重点实验室北京 100191

投稿日期:2011-09-10 修回日期:2011-11-18 发布日期:2011-12-19
通讯作者: 杨树平
基金资助:
国家自然科学基金(No. 30901815)和淮海工学院自然科学基金(No. Z2009019)资助项目.

Synthesis, Crystal Structure and Antibacterial Activity of A Bismuth(III) Complex [Bi₂(PPA)₆?(Phen)₂] with Phenylacetic Acid and 1,10-Phenanthroline

Yang Shuping^a, Han Lijun^b, Pan Yan^c, Wu Zhenming^a, He Xinran^a, Chen Lijuan^a

a School of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005;
b School of Mathematics and Science, Huaihai Institute of Technology, Lianyungang 222005;
c Department of Pharmacology, School of Basic Medical Sciences and State Key Laboratory of Natural and Biomimetic Drugs, Peking University, Beijing 100191

Received:2011-09-10 Revised:2011-11-18 Published:2011-12-19
Supported by:
Project supported by the National Natural Science Foundation of China (No. 30901815) and Natural Science Foundation of Huaihai Institute of Technology, China (No. Z2009019).

A bismuth(III) complex [Bi₂(PPA)₆·(Phen)₂] (HPPA ＝ phenylacetic acid; Phen ＝ 1,10-phenanthroline) was synthesized and characterized by elemental analysis and infrared (IR) spectroscopy, its crystal structure was determined by single crystal X-ray diffraction. The crystal of bismuth(III) complex belongs to triclinic system with space group P-1, a＝0.9100(6) nm, b＝1.2617(8) nm, c＝ 1.3324(9) nm, α＝89.757(8)°, β＝87.277(8)°, γ＝81.155(8)°, V＝1.5099(17) nm³, D_c＝1.748 g·cm^-3, μ＝5.890 mm^-1, Z＝1, F(000)＝780, residual factors R₁＝0.0484, wR₂＝0.1090 [I>2σ(I)], S＝1.002. The comcomplex is a binuclear bismuth(III) compound, and every bismuth(III) atom is nine-coordinated by six O atoms from three ligands (PPA) and two N atoms from one ligand (Phen) and one bridged O atom, and the coordination polyhedron around the bismuth(III) atom can be best described as a distorted tricapped trigonal-prismatic tetrakaidecahedron geometry, the valence sum of around Bi atom V_Bi(1)＝2.897. The distance of Bi…Bi is 0.4469(2) nm. The complex has a good effect against E. Coli, S. Aureus and B. Subtilis.

Key words: bismuth(III) complex, crystal structure, antibacterial activity, phenylacetic acid, 1,10-phenanthroline

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Yang Shuping, Han Lijun, Pan Yan, Wu Zhenming, He Xinran, Chen Lijuan. Synthesis, Crystal Structure and Antibacterial Activity of A Bismuth(III) Complex [Bi₂(PPA)₆?(Phen)₂] with Phenylacetic Acid and 1,10-Phenanthroline[J]. Acta Chimica Sinica, 2012, 0(04): 519-524.

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铋(III)苯乙酸-1,10-邻菲罗啉三元配合物[Bi₂(PPA)₆·(Phen)₂]的合成、晶体结构及抑菌活性

Synthesis, Crystal Structure and Antibacterial Activity of A Bismuth(III) Complex [Bi₂(PPA)₆?(Phen)₂] with Phenylacetic Acid and 1,10-Phenanthroline

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铋(III)苯乙酸-1,10-邻菲罗啉三元配合物[Bi2(PPA)6·(Phen)2]的合成、 晶体结构及抑菌活性