Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (1): 88-94. Previous Articles     Next Articles

新型C60衍生物的合成及其太阳能电池性能

郑立平1, 周清梅1, 王飞1, 邓先宇1, 俞刚1, 曹镛1, 宁滨2, 郭志新2   

  1. 1. 华南理工大学聚合物材料与器件研究所, 广州, 510640;
    2. 中国科学院化学研究所, 北京, 100080
  • 收稿日期:2003-04-02 修回日期:2003-09-24 出版日期:2004-01-14 发布日期:2014-01-26
  • 通讯作者: 曹镛 E-mail::E-mail:poycao@scut.edu.cn
  • 基金资助:
    国家自然科学基金(No.50028302)及科技部973(No.2002CB613404)资助项目.

Synthesis of Three Novel C60 Derivatives and Their Photovoltaic Cell Performance

ZHENG Li-Ping1, ZHOU Qing-Mei1, WANG Fei1, DENG Xian-Yu1, YU Gang1, CAO Yong1, NING Bin2, GUO Zhi-Xin 2   

  1. 1. Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Guangzhou 510640;
    2. Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080
  • Received:2003-04-02 Revised:2003-09-24 Online:2004-01-14 Published:2014-01-26

Three different synthetic routes were used to synthesize different C 60 derivatives: azoalkane cycloaddition, Bingle-Hirsch reaction and Prato reaction. With different chemical structures, these three compounds have different acceptor strengths. These C 60 derivatives together with -phenyl C61-butyric acid methyl ester (PCBM) were used for fabrication of solar cells in blend with poly(2-methoxy-5-(2′-ethylhexoxy)-p-phenylene)(MEH-PPV). It was shown that photovoltaic cell performance varies with acceptor structure and the solubility of the C 60 derivatives in organic solvent. Energy conversion efficiency of one of the synthesized methanofullerene-phenyl C 61-butyric acid butyl ester (PCBB), shows better performance than that of PCBM.

Key words: photovoltaic cell, conjugated polymer, fullerene