Synthesis and Interfacial Properties of Glucosamide-based Trisiloxane Surfactants

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (7): 733-737. Previous Articles Next Articles

新型含硅表面活性剂的合成及性能研究

韩富^1,2, 张高勇^1,2

1. 武汉大学化学与分子科学学院, 武汉, 430072;
2. 中国日用化学工业研究院, 太原, 030001

投稿日期:2003-07-04 修回日期:2003-12-10 发布日期:2014-02-18
通讯作者: 张高勇,E-mail:hanrichli@yahoo.com.cn E-mail:hanrichli@yahoo.com.cn

Synthesis and Interfacial Properties of Glucosamide-based Trisiloxane Surfactants

HAN Fu^1,2, ZHANG Gao-Yong^1,2

1. School of Chemistry & Molecule Science, Wuhan University, Wuhan 430072;
2. China Research Institute of Daily Chemical Industry, Taiyuan 030001

Received:2003-07-04 Revised:2003-12-10 Published:2014-02-18

Abstract

A new family of glucosamide-based trisiloxanes of the general formula Me₃SiOSiMeR¹OSiMe₃[R¹=(CH₂)₃NR²(CH₂)₂NHCO(CHOH)₄CH₂OH; R²=H, CH₂CH(OH)CH₂O(CH₂CH₂O)_xCH₃, x=1, 2, 3 [ST5HZ](1a, 2a～2c)] and (CH₂OCH₂)_y(Me₃SiOSiMeR³OSiMe₃)₂[R³=(CH₂)₃NR⁴(CH₂)₂NHCO(CHOH)₄CH₂OH; R⁴=CH₂CH(OH)CH₂OCH₂, y=0, 1, 2] (3a～3c) have been prepared and characterized. They were prepared by the amidation of the amine functional trisiloxane with the D-gluconic acid δ-lactone and then by the alkylation of the secondary amine with the oligoethylene glycol methyl glycidyl ethers or the oligoethylene glycol diglycidyl ethers. They were structurally characterized by proton, ¹³C NMR and elemental analysis. The interfacial properties of this family of glucosamide-based trisiloxanes were studied. Members of this family reduced the surface tension of water to approximately 21 mN·m^-1 at concentration levels of 10^-4 and 10^-5 mol·L^-1.

Key words: trisiloxane, glucosamide, gemini, synthesis, interfacial property

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HAN Fu, ZHANG Gao-Yong. Synthesis and Interfacial Properties of Glucosamide-based Trisiloxane Surfactants[J]. Acta Chimica Sinica, 2004, 62(7): 733-737.

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新型含硅表面活性剂的合成及性能研究

Synthesis and Interfacial Properties of Glucosamide-based Trisiloxane Surfactants

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