Porous Metal-Organic Frameworks Lithium Metal Anode Protection Layer towards Long Life Li-O2 Batteries

doi:10.6023/A20070290

Acta Chimica Sinica ›› 2020, Vol. 78 ›› Issue (12): 1434-1440.DOI: 10.6023/A20070290 Previous Articles Next Articles

Article

多孔金属有机框架材料作为锂金属负极保护层助力长寿命锂氧气电池

于越^a,b, 张新波^a,b

a 中国科学院长春应用化学研究所稀土资源利用国家重点实验室长春 130022;
b 中国科学技术大学合肥 230026

投稿日期:2020-07-18 发布日期:2020-10-15
通讯作者: 张新波 E-mail:xbzhang@ciac.ac.cn
基金资助:
项目受国家重点研发计划（No.2016YFB0100103）、中华人民共和国国防科技工业（No.JCKY2016130B010）和国家自然科学基金（Nos.21725103，21771013）资助.

Porous Metal-Organic Frameworks Lithium Metal Anode Protection Layer towards Long Life Li-O₂ Batteries

Yu Yue^a,b, Zhang Xinbo^a,b

a State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;
b University of Science and Technology of China, Hefei 230026, China

Received:2020-07-18 Published:2020-10-15
Supported by:
Project supported by the National Key R&D Program of China (No. 2016YFB0100103), the Technology and Industry for National Defence of the People’s Republic of China (No. JCKY2016130B010), and the National Natural Science Foundation of China (Nos. 21725103, 21771013).

1. Supporting Information-A20070290.pdf(1751KB)

Abstract

Among the numerous successors of Li-ion batteries, Li-O₂ cells become promising candidates because of their higher theoretical energy density (3500 Wh·kg^-1). However, the uncontrolled dendrite growth and serious corrosion issues of lithium metal anode are major bottlenecks for practical application of Li-O₂ batteries. To solve the above challenges, herein, we prepared metal-organic frameworks materials (MOF-801) with high specific surface area and abundant pores as a protection layer on lithium metal anode in Li-O₂ batteries. In this manuscript, pure and cubic-shaped MOF-801 materials are successfully synthesized and the high specific surface area (762.9 m²·g^-1) is confirmed. And MOF-801 is verified stable enough as a protection layer towards lithium metal anode and tetraethylene glycol dimethyl ether (TEGDME) 1 mol·L^-1 LiCF₃SO₃ electrolyte system. Due to the rich pore structures and high specific surface area, MOF-801 can assist to form uniform Li⁺ flux and dendrite-free lithium deposition morphology can be confirmed in the scanning electron microscope images, which can avoid the short circuit even fire disaster from the uncontrollable dendrite growth. Besides, the shield effect as well as the water capture function of MOF-801 protection layer can also effectively prevent serious side reactions from the shuttle effect of the contaminants (H₂O, O₂ and strong oxidizing species). Consequently, this strategy enables stable electrode/electrolyte interface and achieves 800 h plating/stripping cycles under a low overpotential of 0.023 V. In contrast, the batteries without protection can only run for 254 h with the overpotential as high as 5 V at last. The electrochemical impedance spectroscopy results also verify that the much lower impedance of the lithium metal anode after protection. When applied in practical Li-O₂ batteries with a fixed capacity of 1000 mAh·g^-1 at a current density of 500 mA·g^-1, stable and long-life cycle performance (170 cycles) has been realized in the Li-O₂ batteries with MOF-801 protection layer, which is 2.88 times longer than those without protection. The batteries with MOF-801 protection layer also deliver a high discharge specific capacity of 8935 mAh·g^-1. This unique protection layer design strategy illustrates fresh insight towards protection strategy in alkali metal anode batteries.

Key words: Li-O₂ battery, lithium metal anode, metal-organic frameworks, dendrite suppression, lithium corrosion

Cite this article

Yu Yue, Zhang Xinbo. Porous Metal-Organic Frameworks Lithium Metal Anode Protection Layer towards Long Life Li-O₂ Batteries[J]. Acta Chimica Sinica, 2020, 78(12): 1434-1440.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

References

[1] Yang, X. Y.; Feng, X. L.; Jin, X.; Shao, M. Z.; Yan, B. L.; Yan, J. M.; Zhang, Y.; Zhang, X. B. Angew. Chem. Int. Ed. 2019, 58, 16411.
[2] Wang, X.; Li, Y.; Bi, X.; Ma, L.; Wu, T.; Sina, M.; Wang, S.; Zhang, M.; Alvarado, J.; Lu, B.; Banerjee, A.; Amine, K.; Lu, J.; Meng, Y. S. Joule 2018, 2, 2381.
[3] Sun, Y.; Zhao, Y.; Wang, J.; Liang, J.; Wang, C.; Sun, Q.; Lin, X.; Adair, K. R.; Luo, J.; Wang, D.; Li, R.; Cai, M.; Sham, T. K.; Sun, X. Adv. Mater. 2019, 31, e1806541.
[4] Li, Z.; Liu, K.; Fan, K.; Yang, Y.; Shao, M.; Wei, M.; Duan, X. Angew. Chem. Int. Ed. 2019 58, 3962.
[5] Lei, X.; Liu, X.; Ma, W.; Cao, Z.; Wang, Y.; Ding, Y. Angew. Chem. Int. Ed. 2018, 57, 16131.
[6] Kang, T.; Wang, Y.; Guo, F.; Liu, C.; Zhao, J.; Yang, J.; Lin, H.; Qiu, Y.; Shen, Y.; Lu, W.; Chen, L. ACS Central Sci. 2019, 5, 468.
[7] Mun, S. K.; Deepika; Seung, H. L.; Min, S. K.; Ji, H. R.; Kwang, R. L.; Lynden, A. A.; Won, I. C. Sci. Adv. 2019, 5, eaax5587.
[8] Bay, M. C.; Wang, M.; Grissa, R.; Heinz, M. V. F.; Sakamoto, J.; Battaglia, C. Adv. Energy Mater. 2019, 10, 1902899.
[9] Yu, Y.; Yin, Y.-B.; Ma, J.-L.; Chang, Z.-W.; Sun, T.; Zhu, Y.-H.; Yang, X.-Y.; Liu, T.; Zhang, X.-B. Energy Storage Mater. 2019, 18, 382.
[10] Yu, Y.; Zhang, X.-B. Matter 2019, 1, 881.
[11] Tong, B.; Huang, J.; Zhou, Z.; Peng, Z. Adv. Mater. 2018, 30, 1704841.
[12] Chen, Z.; Liu, J.; Cui, H.; Zhang, L.; Su, C. Acta Chim. Sinica 2019, 77, 242(in Chinese). (陈之尧, 刘捷威, 崔浩, 张利, 苏成勇, 化学学报, 2019, 77, 242.)
[13] Liu, Z.; Li, W.; Liu, H.; Zhuang, X.; Li, S. Acta Chim. Sinica 2019, 77, 323(in Chinese). (刘治鲁, 李炜, 刘昊, 庄旭东, 李松, 化学学报, 2019, 77, 323.)
[14] Wang, L.; Yang, G.; Wang, J.; Wang, S.; Peng, S.; Yan, W. Acta Chim. Sinica 2018, 76, 666(in Chinese). (王玲, 杨国锐, 王嘉楠, 王思岚, 彭生杰, 延卫, 化学学报, 2018, 76, 666.)
[15] Zeng, J.; Wang, X.; Zhang, X.; Zhuo, R. Acta Chim. Sinica 2019, 77, 1156(in Chinese). (曾锦跃, 王小双, 张先正, 卓仁禧, 化学学报, 2019, 77, 1156.)
[16] Zhang, X.; Wang, X.; Fan, W.; Sun, D. Chinese J. Chem. 2020, 38, 509.
[17] Zheng, S.; Li, X.; Yan, B.; Hu, Q.; Xu, Y.; Xiao, X.; Xue, H.; Pang, H. Adv. Energy Mater. 2017, 7, 1602733.
[18] Zhao, R.; Liang, Z.; Zou, R.; Xu, Q. Joule 2018, 2, 2235.
[19] Liang, Z.; Qu, C.; Guo, W.; Zou, R.; Xu, Q. Adv. Mater. 2018, 30, e1702891.
[20] Li, S.; Dong, Y.; Zhou, J.; Liu, Y.; Wang, J.; Gao, X.; Han, Y.; Qi, P.; Wang, B. Energy Environ. Sci. 2018, 11, 1318.
[21] Zhu, M.; Li, B.; Li, S.; Du, Z.; Gong, Y.; Yang, S. Adv. Energy Mater. 2018, 8, 1703505.
[22] Wang, Z.; Wang, Z.; Yang, L.; Wang, H.; Song, Y.; Han, L.; Yang, K.; Hu, J.; Chen, H.; Pan, F. Nano Energy 2018, 49, 580.
[23] Wang, L.; Zhu, X.; Guan, Y.; Zhang, J.; Ai, F.; Zhang, W.; Xiang, Y.; Vijayan, S.; Li, G.; Huang, Y.; Cao, G.; Yang, Y.; Zhang, H. Energy Storage Mater. 2018, 11, 191.
[24] Jiang, Z.; Liu, T.; Yan, L.; Liu, J.; Dong, F.; Ling, M.; Liang, C.; Lin, Z. Energy Storage Mater. 2018, 11, 267.
[25] He, Y.; Qiao, Y.; Chang, Z.; Zhou, H. Energy Environ. Sci. 2019, 12, 2327.
[26] He, Y.; Chang, Z.; Wu, S.; Qiao, Y.; Bai, S.; Jiang, K.; He, P.; Zhou, H. Adv. Energy Mater. 2018, 8, 1802130.
[27] Deng, H.; Chang, Z.; Qiu, F.; Qiao, Y.; Yang, H.; He, P.; Zhou, H. Adv. Energy Mater. 2020, 10, 1903953.
[28] Chu, F.; Hu, J.; Wu, C.; Yao, Z.; Tian, J.; Li, Z.; Li, C. ACS Appl. Mater. Inter. 2019, 11, 3869.
[29] Chang, Z.; Qiao, Y.; Deng, H.; Yang, H.; He, P.; Zhou, H. Energy Environ. Sci. 2020, 13, 1197.
[30] Cao, L.; Lv, F.; Liu, Y.; Wang, W.; Huo, Y.; Fu, X.; Sun, R.; Lu, Z. Chem. Commun. 2015, 51, 4364.
[31] Bai, S.; Sun, Y.; Yi, J.; He, Y.; Qiao, Y.; Zhou, H. Joule 2018, 2, 2117.
[32] Bai, S.; Liu, X.; Zhu, K.; Wu, S.; Zhou, H. Nat. Energy 2016, 1, 16094.
[33] Hanikel, N.; Prevot, M. S.; Yaghi, O. M. Nat. Nanotech. 2020, 15, 348.
[34] Farhad, F.; Markus, J. K.; Eugene, A. K.; Peter, J. W.; Yang, J. J.; Omar, M. Y. Sci. Adv. 2018, 4, eaat3198.
[35] Choi, J. I.; Chun, H.; Lah, M. S. J. Am. Chem. Soc. 2018, 140, 10915.
[36] Amandine, C.; Youssef, B.; Karim, A.; Prashant, M. B.; Renjith, S. P.; Aleksander, S.; Charlotte, M. C.; Guillaume, M.; Mohamed, E. Science 2017, 356, 731.
[37] Zhang, J.; Bai, H. J.; Ren, Q.; Luo, H. B.; Ren, X. M.; Tian, Z. F.; Lu, S. ACS Appl. Mater. Inter. 2018, 10, 28656.
[38] Furukawa, H.; Gandara, F.; Zhang, Y. B.; Jiang, J.; Queen, W. L.; Hudson, M. R.; Yaghi, O. M. J. Am. Chem. Soc. 2014, 136, 4369.
[39] Li, F.; Ohnishi, R.; Yamada, Y.; Kubota, J.; Domen, K.; Yamada, A.; Zhou, H. Chem. Commun. 2013, 49, 1175.
[40] Laoire, C. O.; Mukerjee, S.; Abraham, K. M.; Plichta, E. J.; Hendrickson, M. A. J. Phys. Chem. C 2010, 114, 9178.
[41] Shui, J. L.; Okasinski, J. S.; Kenesei, P.; Dobbs, H. A.; Zhao, D.; Almer, J. D.; Liu, D. J. Nat. Commun. 2013, 4, 2255.
[42] Mitchell, R. R.; Gallant, B. M.; Shao-Horn, Y.; Thompson, C. V. J. Phys. Chem. Lett. 2013, 4, 1060.
[43] Gallant, B. M.; Kwabi, D. G.; Mitchell, R. R.; Zhou, J.; Thompson, C. V.; Shao-Horn, Y. Energy Environ. Sci. 2013, 6, 2518.

多孔金属有机框架材料作为锂金属负极保护层助力长寿命锂氧气电池

Porous Metal-Organic Frameworks Lithium Metal Anode Protection Layer towards Long Life Li-O₂ Batteries

PDF

Supporting Info.

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Bo Sun, Wenwen Ju, Tao Wang, Xiaojun Sun, Ting Zhao, Xiaomei Lu, Feng Lu, Quli Fan. Preparation of Highly-dispersed Conjugated Polymer-Metal Organic Framework Nanocubes for Antitumor Application [J]. Acta Chimica Sinica, 2023, 81(7): 757-762.
[2]	Junchang Chen, Mingxing Zhang, Shuao Wang. Research Progress of Synthesis Methods for Crystalline Porous Materials [J]. Acta Chimica Sinica, 2023, 81(2): 146-157.
[3]	Xiaojuan Li, Ziyu Ye, Shuhan Xie, Yongjing Wang, Yonghao Wang, Yuancai Lv, Chunxiang Lin. Study on Performance and Mechanism of Phenol Degradation through Peroxymonosulfate Activation by Nitrogen/Chlorine Co-doped Porous Carbon Materials [J]. Acta Chimica Sinica, 2022, 80(9): 1238-1249.
[4]	Shishuo Liang, Shusen Kang, Dong Yang, Jianhua Hu. Interficial Engineering of Lithium Metal Anode for Sulfide Solid State Batteries [J]. Acta Chimica Sinica, 2022, 80(9): 1264-1268.
[5]	Xu Yan, Hemi Qu, Ye Chang, Xuexin Duan. Application of Metal-Organic Frameworks in Gas Pre-concentration, Pre-separation and Detection [J]. Acta Chimica Sinica, 2022, 80(8): 1183-1202.
[6]	Fang Liu, Tingting Pan, Xiurong Ren, Weiren Bao, Jiancheng Wang, Jiangliang Hu. Research on Preparation and Benzene Adsorption Performance of HCDs@MIL-100(Fe) Adsorbents [J]. Acta Chimica Sinica, 2022, 80(7): 879-887.
[7]	Linan Cao, Min Wei. Recent Progress of Electric Conductive Metal-Organic Frameworks Thin Film [J]. Acta Chimica Sinica, 2022, 80(7): 1042-1056.
[8]	Shihui Wang, Xiaoyu Xue, Min Cheng, Shaochen Chen, Chong Liu, Li Zhou, Kexin Bi, Xu Ji. High-Throughput Computational Screening of Metal-Organic Frameworks for CH₄/H₂ Separation by Synergizing Machine Learning and Molecular Simulation [J]. Acta Chimica Sinica, 2022, 80(5): 614-624.
[9]	Rong Zhang, Jiangping Liu, Ziyi Zhu, Shumei Chen, Fei Wang, Jian Zhang. Synthesis, Structure and Characterization of Two Ferrocene Functionalized Cadmium Metal Organic Frameworks^※ [J]. Acta Chimica Sinica, 2022, 80(3): 249-254.
[10]	Xusheng Wang, Xu Yang, Chunhui Chen, Hongfang Li, Yuanbiao Huang, Rong Cao. Graphene Quantum Dots Supported on Fe-based Metal-Organic Frameworks for Efficient Photocatalytic CO₂ Reduction^※ [J]. Acta Chimica Sinica, 2022, 80(1): 22-28.
[11]	Yan-Wu Zhao, Xing Li, Fu-Qiang Zhang, Xiang Zhang. Precise Control of the Dimension of Homochiral Metal-Organic Frameworks （MOFs) and Their Luminescence Properties [J]. Acta Chimica Sinica, 2021, 79(11): 1409-1414.
[12]	Huan Liu, Li Li, Ping Li, Guangzhi Zhang, Xun Xu, Hao Zhang, Lingfang Qiu, Hui Qi, Shuwang Duo. In-situ Construction of 2D/3D ZnIn₂S₄/TiO₂ with Enhanced Photocatalytic Performance [J]. Acta Chimica Sinica, 2021, 79(10): 1293-1301.
[13]	Sun Lian, Wang Honglei, Yu Jinshan, Zhou Xingui. Recent Progress on Proton-Conductive Metal-Organic Frameworks and Their Proton Exchange Membranes [J]. Acta Chimica Sinica, 2020, 78(9): 888-900.
[14]	Zhang Jinwei, Li Ping, Zhang Xinning, Ma Xiaojie, Wang Bo. Water Adsorption Properties and Applications of Stable Metal-organic Frameworks [J]. Acta Chimica Sinica, 2020, 78(7): 597-612.
[15]	Wu Qianye, Zhang Chenxi, Sun Kang, Jiang Hai-Long. Microwave-Assisted Synthesis and Photocatalytic Performance of a Soluble Porphyrinic MOF [J]. Acta Chimica Sinica, 2020, 78(7): 688-694.