有机化学 ›› 2003, Vol. 23 ›› Issue (7): 636-645. 上一篇    下一篇

研究论文

手性双核催化剂在不对称合成中的应用研究进展

张占金;万伯顺;陈惠麟   

  1. 中国科学院大连化学物理研究所
  • 发布日期:2003-07-25

Progress of Application of Chiral Binuclear Complex Catalyst to the Asymmetric Synthesis

Zhang Zhanjin;Wan Boshun;Chen Huilin   

  1. Dalian Institue of Chemical Physics, Chinese Academy of Sciences
  • Published:2003-07-25

综述了含相同金属的手性双核铑配合物、手性以核钯配合物、手性双核钛配合 物、手性双核铜配合物等催化体系在烯烃的环丙烷化、亚胺的烯丙基化、氰硅化、 缩合等不对称合成中的应用。

关键词: 双核络合物;不对称合成;铑络合物;钯络合物;钛络合物;烯烃, 环丙烷;亚胺;烯丙基化;应用

The application of the same metallic chiral binuclear complexes containing rhodium, palladium, titanium, copper and so on to the asymmetric cyclopiopanation reaction, cyanosilylation reaction, allylation reaction, aldol reaction and so on is reviewed.

Key words: DINUCLEAR COMPLEX;ASYMMETRICAL SYNTHESIS;RHODIUM COMPLEX;PALLADIUM COMPLEX, TITANIUM COMPLEX;ALKENE;CYCLOPROPANE;IMINE;ALLYLATION;APPLICATION

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