Microporous Network Polyaniline Coated Magnetic Fe3O4 Nanoparticals Supported Palladium Catalyzed Suzuki and Heck Coupling Reactions

doi:10.6023/cjoc201503014

Chin. J. Org. Chem. ›› 2015, Vol. 35 ›› Issue (8): 1673-1681.DOI: 10.6023/cjoc201503014 Previous Articles Next Articles

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多孔网状聚苯胺包覆磁性纳米Fe₃O₄负载钯催化的Suzuki及Heck偶联反应

黑莉楹^a,b, 冯翠兰^b, 李珍^a,b, 刘澜涛^b, 桂建舟^a

a 辽宁石油化工大学抚顺 113001;
b 商丘师范学院商丘 476000

收稿日期:2015-03-12 修回日期:2015-04-19 发布日期:2015-04-27
通讯作者: 冯翠兰 E-mail:fengcuilanfan@163.com
基金资助:
国家自然科学基金(Nos. 21102087, 21202095)资助项目.

Microporous Network Polyaniline Coated Magnetic Fe₃O₄ Nanoparticals Supported Palladium Catalyzed Suzuki and Heck Coupling Reactions

Hei Liying^a,b, Feng Cuilan^b, Li Zhen^a,b, Liu Lantao^b, Gui Jianzhou^a

a College of Chemistry and Material Science, Liaoning Shihua University, Fushun 113000;
b College of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu 476000

Received:2015-03-12 Revised:2015-04-19 Published:2015-04-27
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21102087, 21202095).

1. Microporous Network Polyaniline Coated Magnetic Fe₃O₄ Nanoparticals Supported Palladium Catalyzed Suzuki and Heck Coupling Reactions.PDF(1566KB)

Abstract

To solve the recovery and recycling problem of homogeneous palladium catalyst, a cheap and convenient method was developed for the synthesis of magnetic nanoparticles (MNPs) supported palladium catalyst Fe₃O₄@MOPPA-Pd which is easily in situ separated from the reaction system by the application of a permanent magnet. The catalyst can highly catalyzed the Suzuki reaction and Heck reaction of different halogenobenzenes. Especially, it has higher catalytic activity for Suzuki coupling reaction. Under mild reaction conditions, 300 mmol of bromobenzene reacted with phenylboronic acid catalyzed by 10 mg of Fe₃O₄@MOPPA-Pd can give the product with 98% yield. And the turnover number (TON) and turnover frequency (TOF) of the catalyst reached 77052 and 51368 h^-1, respectively. In addition, Fe₃O₄@MOPPA-Pd can be easily separated from reaction system in the presence of magnetic field and the catalytic activity was not decreased by at least 4 times recycles.

Key words: magnetic nanoparticles, supported palladium catalyst, C—C coupling reaction, Suzuki coupling reaction, Heck coupling reaction

Cite this article

Hei Liying, Feng Cuilan, Li Zhen, Liu Lantao, Gui Jianzhou. Microporous Network Polyaniline Coated Magnetic Fe₃O₄ Nanoparticals Supported Palladium Catalyzed Suzuki and Heck Coupling Reactions[J]. Chin. J. Org. Chem., 2015, 35(8): 1673-1681.

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多孔网状聚苯胺包覆磁性纳米Fe₃O₄负载钯催化的Suzuki及Heck偶联反应

Microporous Network Polyaniline Coated Magnetic Fe₃O₄ Nanoparticals Supported Palladium Catalyzed Suzuki and Heck Coupling Reactions

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多孔网状聚苯胺包覆磁性纳米Fe3O4负载钯催化的Suzuki及Heck偶联反应