Magnetic Microporous Organic Polymer of 1,1'-Bi-2-naphtholSupported Palladium for Suzuki Coupling Reactions

doi:10.6023/cjoc201507028

Chin. J. Org. Chem. ›› 2016, Vol. 36 ›› Issue (1): 179-184.DOI: 10.6023/cjoc201507028 Previous Articles Next Articles

Articles

磁性微孔聚1,1'-联二萘酚负载钯催化的Suzuki偶联反应

冯翠兰, 黑莉楹, 李珍, 刘澜涛

商丘师范学院商丘 476000

收稿日期:2015-07-23 修回日期:2015-08-22 发布日期:2015-09-06
通讯作者: 冯翠兰, 刘澜涛 E-mail:liult05@iccas.ac.cn
基金资助:
国家自然科学基金(Nos. 21102087, 21202095)资助项目.

Magnetic Microporous Organic Polymer of 1,1'-Bi-2-naphtholSupported Palladium for Suzuki Coupling Reactions

Feng Cuilan, Hei Liying, Li Zhen, Liu Lantao

College of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu 476000

Received:2015-07-23 Revised:2015-08-22 Published:2015-09-06
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21102087, 21202095).

1. Magnetic Microporous Organic Polymer of 1,1'-Bi-2-naphtholSupported Palladium for Suzuki Coupling Reactions.PDF(764KB)

Abstract

A recyclable palladium catalyst supported on magnetic microporous organic polymer (MOP) of 1,1'-bi-2-naphthol (Fe₃O₄@MOPB-Pd) was synthesized by two steps. After being charactered by transmission electron microscope (TEM), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TG) and vibrating sample magnetometer (VSM), the palladium catalyst was applied in Suzuki coupling reaction in air atmosphere. With 0.01 g of Fe₃O₄@MOPB-Pd (0.12 mol% Pd based on bromobenzene) as catalyst, 1.0 mmol of bromobenzene reacted with 1.1 equiv. phenylboronic acid at 60 ℃ for 3 h can give the product with 98% yield. In addition, Fe₃O₄@MOPB-Pd can be easily separated from reaction system in the presence of magnetic field and the 92% yield was achieved even being used at 7th time for the Suzuki coupling reaction of iodobenzene and phenylboronic acid.

Key words: magnetic nanoparticles, supported Pd catalyst, suzuki coupling reaction, BINOL, MOPs

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Feng Cuilan, Hei Liying, Li Zhen, Liu Lantao. Magnetic Microporous Organic Polymer of 1,1'-Bi-2-naphtholSupported Palladium for Suzuki Coupling Reactions[J]. Chin. J. Org. Chem., 2016, 36(1): 179-184.

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磁性微孔聚1,1'-联二萘酚负载钯催化的Suzuki偶联反应

Magnetic Microporous Organic Polymer of 1,1'-Bi-2-naphtholSupported Palladium for Suzuki Coupling Reactions

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