Chin. J. Org. Chem. ›› 2015, Vol. 35 ›› Issue (11): 2301-2312.DOI: 10.6023/cjoc201505039 Previous Articles     Next Articles

Reviews

磷氰酸根负离子的合成及其在含磷有机(杂环)化合物合成中的应用研究进展

权正军, 王文鹏, 王喜存   

  1. 西北师范大学化学化工学院 兰州 730070
  • 收稿日期:2015-05-26 修回日期:2015-07-01 出版日期:2015-11-25 发布日期:2015-07-08
  • 通讯作者: 权正军, 王喜存 E-mail:quanzhengjun@hotmail.com;wangxicun@nnwu.edu.cn
  • 基金资助:

    国家自然科学基金(Nos. 21362032, 21362031, 21562036)资助项目.

Recent Advances in the Synthesis and the Reactivity of 2-Phosphaethynolate Anion

Quan Zhengjun, Wang Wenpeng, Wang Xicun   

  1. College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070
  • Received:2015-05-26 Revised:2015-07-01 Online:2015-11-25 Published:2015-07-08
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21362032, 21362031, 21562036).

Since Becker and co-workers isolated the 2-phosphaethynolate anion (P≡C—O-) in 1992, the synthesis of 2-phosphaethynolate anion and its utilizations in the synthesis of phosphorus-containing organic compounds and heterocycles have been gained much attentions. This review mainly summarizes the recently reported methods for the synthesis of 2-phosphaethynolate anions and its utilizations in the synthesis of organophosphorus compounds containing their versatility, substrate scope and limitation.

Key words: 2-phosphaethynolate anion, organophosphorus chemistry, cycloaddition