Chin. J. Org. Chem. ›› 2016, Vol. 36 ›› Issue (3): 460-479.DOI: 10.6023/cjoc201511026 Previous Articles     Next Articles




  1. 环境友好化学与应用教育部重点实验室 特种高分子材料湖南省重点实验室 湘潭大学化学学院 湘潭 411105
  • 收稿日期:2015-11-15 修回日期:2015-12-30 发布日期:2016-01-07
  • 通讯作者: 陈华杰
  • 基金资助:

    国家自然科学基金(No. 51403177)、湖南省自然科学基金(No. 2015JJ3122)、中国博士后基金(Nos. 2015T80877, 2014M552141)和湖南省科技厅(No. 2015RS4025)资助项目.

Recent Advances in High-Mobility Polymeric Semiconductor Materials

Chen Huajie   

  1. Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, Key Laboratory of Advanced Functional Polymeric Materials of College of Hunan Province, College of Chemistry, Xiangtan University, Xiangtan 411105
  • Received:2015-11-15 Revised:2015-12-30 Published:2016-01-07
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 51403177), the Natural Science Foundation of Hunan Province (No. 2015JJ3122), the China Postdoctoral Science Foundation (Nos. 2015T80877, 2014M552141), and the Science and Technology Planning Project of Hunan Province (No. 2015RS4025).

Significant progress has been made in polymeric semiconductors and their organic field-effect transistors (OFETs) since 1980s. To date, hundreds of polymeric semiconductors have been reported and used for OFETs. The hole mobility above 36.3 cm2·V-1·s-1 has been achieved, which can be competitive with organic small semiconductors and even amorphous silicon. In this review, the recent progress in high-mobility polymeric semiconductor materials has been summarized from the perspective of design, synthesis, and OFET devices performance. Moreover, the recent developments are systematically summarized and analyzed according to different types of polymeric semiconductors, including p-type, n-type, and ambipolar polymeric semiconductors. The analysis about the relationship among the molecular structure-aggregation structure-OFET devices performance may guide the rational molecule design in the polymeric semiconductor materials with excellently comprehensive performance in the future.

Key words: organic field-effect transistors, polymer semiconductors, high mobility, air stability