Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (11): 2948-2955.DOI: 10.6023/cjoc201705027 Previous Articles     Next Articles



袁航a, 陈惠莲a, 罗治斌b, 高玉华a, 陆鸿飞a   

  1. a 江苏科技大学环境与化学工程学院 镇江 212003;
    b 江苏大学化工学院 镇江 212003
  • 收稿日期:2017-05-17 修回日期:2017-07-13 发布日期:2017-08-11
  • 通讯作者: 陆鸿飞
  • 基金资助:


Synthesis of a Pd-Pyridine N-Heterocyclic Carbene Complex (NHC)-PdCl2(Py) and Its Efficient Application in Coupling Reaction

Yuan Hanga, Chen Huiliana, Luo Zhibinb, Gao Yuhuaa, Lu Hongfeia   

  1. a School of Envionmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003;
    b School of Chemical Engineering, Jiangsu University, Zhenjiang 212003
  • Received:2017-05-17 Revised:2017-07-13 Published:2017-08-11
  • Contact: 10.6023/cjoc201705027
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21402067).

A Pd-pyridine N-heterocyclic carbene complex (NHC)PdCl2(Py) has been synthesized through two steps and successfully applied as an effective catalyst for the Suzuki coupling reaction, Heck coupling reaction and Sonogashira coupling reaction. The catalyst demonstrates excellent catalytic activity in Suzuki coupling reaction and Sonogashira coupling reaction with a catalyst loading of 0.1 mol% and 1 mol% in Heck coupling reaction.

Key words: carbene, suzuki coupling, Heck coupling, Sonogashira coupling