Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (6): 1556-1561.DOI: 10.6023/cjoc201712038 Previous Articles     Next Articles

Notes

无碱条件下的Cu2O催化绿色氧化端基炔偶联

马楠, 曾祥华   

  1. 嘉兴学院生物与化学工程学院 嘉兴 314001
  • 收稿日期:2017-12-27 修回日期:2018-01-31 出版日期:2018-06-25 发布日期:2018-02-11
  • 通讯作者: 曾祥华,E-mail:xianghuazeng@mail.zjxu.edu.cn E-mail:xianghuazeng@mail.zjxu.edu.cn
  • 基金资助:

    浙江省自然科学基金(No.LY17B030011)及嘉兴市科技计划(No.2015AY11014)资助项目.

Cu2O-Catalyzed Green Oxidative Terminal Alkynes Homocoupling without Bases

Ma Nan, Zeng Xianghua   

  1. College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing 314001
  • Received:2017-12-27 Revised:2018-01-31 Online:2018-06-25 Published:2018-02-11
  • Contact: 10.6023/cjoc201712038 E-mail:xianghuazeng@mail.zjxu.edu.cn
  • Supported by:

    Project supported by the National Natural Science Foundation of Zhejiang Province (No. LY17B030011) and the Jiaxing Science and Technology Project (No. 2015AY11014).

A high efficient method for the synthesis of 1,3-diynes derivatives which employed terminal alkynes as the substrates and copper(I) oxide as the catalyst was developed. This method possessed the character of base-free and mild reaction conditions. The reaction mechanism was also studied. Furthermore, this reaction could be magnified to gram scale and the catalyst of copper(I) oxide could be recycled.

Key words: copper (I) oxide, homocoupling, terminal alkynes, base-free