Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (10): 2501-2518.DOI: 10.6023/cjoc201805016 Previous Articles     Next Articles

Special Issue: 碳氢活化合辑2018-2019 元素有机化学合辑2018-2019



闫溢哲a,b, 崔畅a, 李政a   

  1. a 郑州轻工业学院食品与生物工程学院 郑州 450000;
    b 食品生产与安全河南省协同创新中心 郑州 450000
  • 收稿日期:2018-05-06 修回日期:2018-05-30 发布日期:2018-06-15
  • 通讯作者: 闫溢哲,
  • 基金资助:


Recent Advances in Oxidative Coupling Reaction Catalyzed by Low-Valence Iodine

Yan Yizhea,b, Cui Changa, Li Zhenga   

  1. a School of Food and Biological Engineering, Zhengzhou University of Light Industry, Zhengzhou 450000;
    b Henan Collaborative Innovation Center of Food Production and Safety, Zhengzhou 450000
  • Received:2018-05-06 Revised:2018-05-30 Published:2018-06-15
  • Contact: 10.6023/cjoc201805016
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21502177), the Scientific and Technological Breakthrough Plan of Henan Province (No. 182102310903) and the Doctoral Research Foundation of Zhengzhou University of Light Industry (No. 2014BSJJ032).

In recent years, low-valence iodine-catalyzed oxidative coupling reaction has made rapid progress, providing an effective method for the construction of C—C, C—O, C—N, C—S, C—P and other chemical bonds. Compared with the transition metal-catalyzed oxidation coupling reaction, this protocol is metal-free under mild conditions. It avoids the high cost and toxicity of transition metal catalyst, which meets the requirements of green chemistry. Therefore, iodine catalysis has attracted much attention of the synthetic chemists. The research progress on low-valence iodine-catalyzed oxidative coupling from 2010 to now is summarized, and outlook of this field is also prospected.

Key words: low-valence iodine, oxidative coupling, chemical bond, atom economy