Chin. J. Org. Chem. ›› 2019, Vol. 39 ›› Issue (2): 301-317.DOI: 10.6023/cjoc201807028 Previous Articles     Next Articles

REVIEW

过渡金属催化联烯胺环化反应进展

耿佃国   

  1. 淄博职业学院 淄博 255314
  • 收稿日期:2018-07-17 修回日期:2018-09-06 出版日期:2019-02-25 发布日期:2018-09-26
  • 通讯作者: 耿佃国 E-mail:gengdianguo@126.com

Recent Advances on Transition-Metal-Catalyzed Allenamides Cyclization

Geng Dianguo   

  1. Zibo Vocational Institute, Zibo 255314
  • Received:2018-07-17 Revised:2018-09-06 Online:2019-02-25 Published:2018-09-26
  • Contact: 10.6023/cjoc201807028 E-mail:gengdianguo@126.com

With the especial reactivity, selectivity, availability and stability, the allenamides have got more and more attention, and the reports on allenamides cyclization grow rapidly. This review gives an up-to-date overview of transition-metal-catalyzed allenamides cyclization, which are sorted by metal catalysts in eight categories of Pd, Ru, Rh, Au, Co, Ag, Pt and Ni. For most of these transformations, the plausible mechanisms are demonstrated in details. Clarification of these issues is the key point for understanding the transition-metal-catalyzed allenamides cyclization and developing new high performance methodologies for chemists.

Key words: allenamides, cyclization, heterocyclic compounds, transition metal catalysis