Chin. J. Org. Chem. ›› 2019, Vol. 39 ›› Issue (4): 1153-1159.DOI: 10.6023/cjoc201811010 Previous Articles     Next Articles

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Cu(Ⅱ)/Ag(I)催化芳香羧酸和邻氨基苯甲酰胺的选择性脱羧胺化反应

沈丽, 张洁, 谢建伟   

  1. 石河子大学化学化工学院/新疆兵团化工绿色过程重点实验室-省部共建国家重点实验室培育基地 石河子 832003
  • 收稿日期:2018-11-05 修回日期:2018-12-15 出版日期:2019-04-25 发布日期:2018-12-28
  • 通讯作者: 谢建伟 E-mail:cesxjw@foxmail.com
  • 基金资助:

    国家自然科学基金(No.21606153,21868032)资助项目.

Cu(Ⅱ)/Ag(I)-Catalyzed Selective Decarboxylated Amination of Aromatic Carboxylic Acids with o-Aminobenzamides

Shen Li, Zhang Jie, Xie Jianwei   

  1. School of Chemistry and Chemical Engineering/Key Laboratory for Green Processing of Chemical Engineering of Xinjian Bingtuan, Shihezi University, Shihezi 832003
  • Received:2018-11-05 Revised:2018-12-15 Online:2019-04-25 Published:2018-12-28
  • Contact: 10.6023/cjoc201811010 E-mail:cesxjw@foxmail.com
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos.21606153,21868032).

Cu(OTf)2/AgOTf-catalyzed selective decarboxylation C-N crossing coupling of o-nitro aromatic carboxylic acids with o-aminobenzamides has been establised, affording seventeen diarylaminobenzamides in moderate yields. The present protocol provides a new choice for selective N-arylation of amines.

Key words: decarboxylation, selective amination, o-nitro aromatic carboxylic acid, o-aminobenzamide