Chinese Journal of Organic Chemistry ›› 2019, Vol. 39 ›› Issue (11): 3207-3214.DOI: 10.6023/cjoc201904069 Previous Articles     Next Articles

基于简单高效钯纳米粒子催化Suzuki偶联反应的研究

李恒超, 赵玲, 刘燕, 张霞, 李王兵, 敬林海, 黄锦*(), 汪伟*()   

  1. 西华师范大学化学化工学院 应用化学研究所 化学合成与污染控制四川省重点实验室 四川南充 637002
  • 收稿日期:2019-04-27 出版日期:2019-11-25 发布日期:2019-07-03
  • 通讯作者: 黄锦,汪伟 E-mail:huahuanhuangjin@163.com;wangwei1987@cwnu.edu.cn
  • 基金资助:
    国家自然科学基金(21602144);四川省科技计划(2018JY0485);西华师范大学科研启动基金(17E049)

An Efficient Palladium Nanoparticles Catalytic System for Suzuki Coupling Reactions

Li Hengchao, Zhao Ling, Liu Yan, Zhang Xia, Li Wangbing, Jing Linhai, Huang Jin*(), Wang Wei*()   

  1. Chemical Synthesis Pollution Control Key Laboratory of Sichuan, Province Institute of Applied Chemistry, College of Chemistry and Chemical Engineering, China West Normal University, Nanchong, Sichuan 637002
  • Received:2019-04-27 Online:2019-11-25 Published:2019-07-03
  • Contact: Huang Jin,Wang Wei E-mail:huahuanhuangjin@163.com;wangwei1987@cwnu.edu.cn
  • Supported by:
    the National Natural Science Foundation of China(21602144);the Sichuan Science and Technology Program(2018JY0485);the Fundamental Research Funds of China West Normal University(17E049)

A simple and highly efficient palladium nanoparticles catalytic system was applied in Suzuki coupling reaction. This system could catalyze a variety of aryl halide and arylboronic acid substrates with a wide range of functional groups. A high turnover number of 90000 was obtained with the catalyst loading as low as 0.001 mol%. This catalyst system exhibited good stability and longevity.

Key words: aryl hailde, arylboronic acid, palladium nanoparticle, Suzuki coupling