Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (12): 4087-4100.DOI: 10.6023/cjoc202005047 Previous Articles     Next Articles


黄远婷, 陈迁   

  1. 广东工业大学轻工化工学院 广州 510006
  • 收稿日期:2020-05-18 修回日期:2020-06-21 发布日期:2020-07-17
  • 通讯作者: 陈迁
  • 基金资助:

Recent Progress in P- and S-Arylation Reactions of Arynes

Huang Yuanting, Chen Qian   

  1. School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006
  • Received:2020-05-18 Revised:2020-06-21 Published:2020-07-17
  • Supported by:
    Project supported by the Science and Technology Planning Project of Guangdong Province (No. 2017A010103044), the 100 Young Talents Programme of Guangdong University of Technology (No. 220413506) and the Basic and Applied Basic Research Foundation of Guangdong Province (No. 2019B1515120035).

Arylphosphine and aryl sulfur compounds have been widely used in organic synthesis, functional materials and pharmaceutical chemistry. Thus, the development of green, mild and highly efficient methodologies for P- and S-arylation is of great importance. Recently, the reactions involving arynes provided a novel approach to the arylation of organophosphorus and organosulfur compounds. These reactions can be performed in the absence of transition metal catalysts under mild conditions with broad scope. The recent progress in P- and S-arylation reactions with arynes is introduced on the basis of different reaction types.

Key words: aryne, organophosphorus, organosulfur, arylation reaction