Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (5): 1055-1068.DOI: 10.6023/cjoc201702050 Previous Articles     Next Articles

REVIEW

简单易得试剂与磷-氢化合物交叉偶联合成有机磷化合物

杨佳a, 肖晶a,c, 周永波a, 陈铁桥a, 尹双凤a, 韩立彪b   

  1. a 湖南大学化学化工学院 化学生物传感与计量学国家重点实验室 长沙 410082;
    b National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8565, Japan;
    c 湖南科技大学 理论有机化学与功能分子教育部重点实验室 湘潭 411201
  • 收稿日期:2017-02-28 修回日期:2017-04-08 发布日期:2017-05-02
  • 通讯作者: 周永波,韩立彪 E-mail:zhouyb@hnu.edu.cn;libiao-han@aist.go.jp
  • 基金资助:

    国家自然科学基金(Nos.21373080,21573065,21273066)和湖南省杰出青年基金(No.2016JJ1007)资助项目.

Recent Advances in the Synthesis of Organophosphorus Compounds via Cross Coupling between Readily Available Materials and P-H Compounds

Yang Jiaa, Xiao Jinga,c, Zhou Yongboa, Chen Tieqiaoa, Yin Shuangfenga, Han Libiaob   

  1. a State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082;
    b National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8565, Japan;
    c Key Laboratory of Theoretical Organic Chemistry and Functional Molecule of the Ministry of Education, Hunan University of Science and Technology, Xiangtan 411201
  • Received:2017-02-28 Revised:2017-04-08 Published:2017-05-02
  • Contact: 10.6023/cjoc201702050 E-mail:zhouyb@hnu.edu.cn;libiao-han@aist.go.jp
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21373080, 21573065, 21273066), and the Natural Science Foundation of Hunan Province (No. 2016JJ1007)

This mini-review focuses on the recent advances in the synthesis of organophosphorus compounds via cross coupling of P-H compounds with readily available starting materials, mainly including the reactions of terminal alkynes and heteroatom compounds (oxygen, sulfur or nitrogen-contained compounds) with P-H compounds forming sp-C-P, sp2-C-P, sp3-C-P, and P-Z bonds. Related reaction mechanisms are also discussed.

Key words: P-H compounds, cross coupling, organophosphorus compounds