Chinese Journal of Organic Chemistry ›› 2021, Vol. 41 ›› Issue (12): 4588-4609.DOI: 10.6023/cjoc202109046 Previous Articles     Next Articles

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光电技术在含硒杂环合成中的应用研究

王薪a, 张艳b, 孙凯b,*(), 孟建萍b, 张冰a,*()   

  1. a 郑州大学化学工程学院 郑州 450001
    b 烟台大学化学与化学工程学院 山东烟台 264005
  • 收稿日期:2021-09-29 修回日期:2021-10-14 发布日期:2021-10-20
  • 通讯作者: 孙凯, 张冰
  • 基金资助:
    国家自然科学基金(21801007)

Study on the Application of Photoelectric Technology in the Synthesis of Selenium-Containing Heterocycles

Xin Wanga, Yan Zhangb, Kai Sunb(), Jianping Mengb, Bing Zhanga()   

  1. a School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001
    b School of Chemistry and Chemical Engineering, Yantai University, Yantai, Shandong 264005
  • Received:2021-09-29 Revised:2021-10-14 Published:2021-10-20
  • Contact: Kai Sun, Bing Zhang
  • Supported by:
    National Natural Science Foundation of China(21801007)

Selenium-containing heterocycles are a kind of important organic molecules, which are widely used in medicine, agrochemicals, organic materials and other fields. Therefore, the introduction of selenium atom into organic molecules is of great significance in synthetic chemistry. Visible light and electrochemical technology is one of the green and sustainable synthesis methods, which has opened up broad application prospects in the fields of bifunctionalization and cyclization of unsaturated bonds and direct functionalization of C—H bonds. In recent years, the development of novel selenium cyclization reaction using photoelectric technology to drive unsaturated bonds and direct selenization reaction of C—H bonds has attracted much attention. Therefore, this paper describes the electrochemical-driven and visible-light-induced synthesis reactions of selenium-containing heterocycles, and discusses the applicable scope and mechanism of some reactions.

Key words: organic selenium compounds, selenium cyclization, alkenes and alkynes, visible light, electrochemistry