Chin. J. Org. Chem. ›› 1992, Vol. 12 ›› Issue (1): 35-40. Previous Articles     Next Articles

Original Articles

某些有机钨卤化物RC~5H~4(CO)~3WX(R=MeCO, MeO~2C, EtO~2C; X=Cl, Br, I)的合成及结构鉴定

宋礼成;董庆;胡青眉   

  1. 南开大学元素有机化学实验室
  • 发布日期:1992-02-25

Synthesis and identification of some organotungsten halides RC~5H~4-(CO)~3WX(R=MeCO, MeO~2C, EtO~2C; X=Cl, Br, I)

SONG LICHENG;DONG QING;HU QINGMEI   

  • Published:1992-02-25

The title organotungsten halides were synthesized via the reactions of RC5H4(CO)3WNa with I2, PX3 (X = Cl, Br, I), PhPCl2, p-CH3C6H4PCl2 or MeAsI2. The single crystal mol. structure with R = MeCO, X = Br) was determine by x-ray diffraction.

Key words: HALIDE, CRYSTAL STRUCTURE DETERMINATION, CYCLOPENTADIENYL GROUP, ORGANO TUNGSTEN COMPOUNDS

CLC Number: