Photoinduced Single Electron Transfer (SET) Cyclizations of N-Linked Biselectrondonor Chain with Dissimilar Leave Groups Phthalimides Derivatives

Chin. J. Org. Chem. ›› 2010, Vol. 30 ›› Issue (07): 1021-1025. Previous Articles Next Articles

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N-(带有不同离去基团的二供电子链)邻苯二甲酰亚胺衍生物的光诱导单电子转移环化反应

谭广慧，魏树权，岳群峰，赵俊明，金英学*

(哈尔滨师范大学化学化工学院哈尔滨 150025)

收稿日期:2009-10-22 修回日期:2009-12-20 发布日期:2010-02-19
通讯作者: 金英学 E-mail:yenghak@hrbnu.edu.cn
基金资助:
国家级.国家自然科学基金

Photoinduced Single Electron Transfer (SET) Cyclizations of N-Linked Biselectrondonor Chain with Dissimilar Leave Groups Phthalimides Derivatives

TAN Guang-Hui, WEI Shu-Quan, YUE Qun-Feng, ZHAO Jun-Ming, JIN Ying-Xue

(College of Chemistry & Chemical Engineering, Harbin Normal University, Harbin 150025)

Received:2009-10-22 Revised:2009-12-20 Published:2010-02-19

Abstract

Phthalimide derivatives with polyethoxy chain and trimethylsily teminated polyethoxy chian occur photoinduced single electron transfer (SET) cyclization reaction in methanol solvent (containing HClO), and could provide cyclocompounds which were participation constituted with the trimethylsily terminated polyethoxy chain in high regioselectivity and good yield. The structures of all new compundswere confirmed by NMR and EI-MS techniques.

Key words: phthalimide, biselectrondonor chain, single electron transfer (SET), cyclization reaction, regioselectivity

Cite this article

TAN Guang-Hui, WEI Shu-Quan, YUE Qun-Feng, ZHAO Jun-Ming, JIN Ying-Xue. Photoinduced Single Electron Transfer (SET) Cyclizations of N-Linked Biselectrondonor Chain with Dissimilar Leave Groups Phthalimides Derivatives[J]. Chin. J. Org. Chem., 2010, 30(07): 1021-1025.

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N-(带有不同离去基团的二供电子链)邻苯二甲酰亚胺衍生物的光诱导单电子转移环化反应

Photoinduced Single Electron Transfer (SET) Cyclizations of N-Linked Biselectrondonor Chain with Dissimilar Leave Groups Phthalimides Derivatives

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