Recent Advances in the Synthesis and the Reactivity of 2-Phosphaethynolate Anion

doi:10.6023/cjoc201505039

Chin. J. Org. Chem. ›› 2015, Vol. 35 ›› Issue (11): 2301-2312.DOI: 10.6023/cjoc201505039 Previous Articles Next Articles

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磷氰酸根负离子的合成及其在含磷有机(杂环)化合物合成中的应用研究进展

权正军, 王文鹏, 王喜存

西北师范大学化学化工学院兰州 730070

收稿日期:2015-05-26 修回日期:2015-07-01 发布日期:2015-07-08
通讯作者: 权正军, 王喜存 E-mail:quanzhengjun@hotmail.com;wangxicun@nnwu.edu.cn
基金资助:
国家自然科学基金(Nos. 21362032, 21362031, 21562036)资助项目.

Recent Advances in the Synthesis and the Reactivity of 2-Phosphaethynolate Anion

Quan Zhengjun, Wang Wenpeng, Wang Xicun

College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070

Received:2015-05-26 Revised:2015-07-01 Published:2015-07-08
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21362032, 21362031, 21562036).

Since Becker and co-workers isolated the 2-phosphaethynolate anion (P≡C—O^-) in 1992, the synthesis of 2-phosphaethynolate anion and its utilizations in the synthesis of phosphorus-containing organic compounds and heterocycles have been gained much attentions. This review mainly summarizes the recently reported methods for the synthesis of 2-phosphaethynolate anions and its utilizations in the synthesis of organophosphorus compounds containing their versatility, substrate scope and limitation.

Key words: 2-phosphaethynolate anion, organophosphorus chemistry, cycloaddition

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Quan Zhengjun, Wang Wenpeng, Wang Xicun. Recent Advances in the Synthesis and the Reactivity of 2-Phosphaethynolate Anion[J]. Chin. J. Org. Chem., 2015, 35(11): 2301-2312.

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磷氰酸根负离子的合成及其在含磷有机(杂环)化合物合成中的应用研究进展

Recent Advances in the Synthesis and the Reactivity of 2-Phosphaethynolate Anion

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