Efficient Synthesis of 5,5-(Phenylmethylene)bis(2,2-dimethyl-1,3-dioxane-4,6-dione) Derivatives in Biobased Gluconic Acid Aqueous Solution

doi:10.6023/cjoc201612044

Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (6): 1560-1564.DOI: 10.6023/cjoc201612044 Previous Articles Next Articles

Notes

生物介质葡萄糖酸水溶液中5，5-（苯基亚甲基）双（2，2-二甲基二噁烷-4，6-二酮）衍生物的有效合成

林春花^a, 袁建军^a, 刘德永^a, 张后富^b, 许招会^a

a. 江西师范大学化学化工学院南昌 330022;
b. 江西省中医药研究院南昌 330026

收稿日期:2016-12-14 修回日期:2017-01-24 发布日期:2017-02-15
通讯作者: 许招会 E-mail:gotoxzh@163.com
基金资助:
国家科技攻关计划（No.2001BA323C）和江西省研究生创新基金（No.YC2015-B023）资助项目.

Efficient Synthesis of 5,5-(Phenylmethylene)bis(2,2-dimethyl-1,3-dioxane-4,6-dione) Derivatives in Biobased Gluconic Acid Aqueous Solution

Lin Chunhua^a, Yuan Jianjun^a, Liu Deyong^a, Zhang Houfu^b, Xu Zhaohui^a

a. Chemistry and Chemical Engineering Department, Jiangxi Normal University, Nanchang 330022;
b. Jiangxi Traditional Chinese Medecine Institute, Nanchang 330026

Received:2016-12-14 Revised:2017-01-24 Published:2017-02-15
Contact: 10.6023/cjoc201612044 E-mail:gotoxzh@163.com
Supported by:
Project supported by the National Science and Technology Project (No. 2001BA323C) and the Graduate Innovation Foundation of Jiangxi Province (No. YC2015-B023).

1. Efficient Synthesis of 5,5-(Phenylmethylene)bis(2,2-dimethyl-1,3-dioxane-4,6-dione) Derivatives in Biobased Gluconic Acid Aqueous Solution.PDF(7931KB)

Abstract

Six kinds of 5,5-(phenylmethylene)bis(2,2-dimethyl-1,3-dioxane-4,6-dione) derivatives were synthesized by the reaction of aromatic aldehydes and 2,2-dimethyl-1,3-dioxane-4,6-dione in biobased gluconic acid aqueous solution at 40 ℃. The reaction has the advantages of high yields (81%~92%), mild conditions, simple operation and environmental friendliness. Furthermore, GAAS can be reused for several times.

Key words: gluconic acid aqueous solution, aromatic aldehydes, 2,2-dimethyl-1,3-dioxane-4,6-dione, 5,5-(phenylmethylene)-bis(2,2-dimethyl-1,3-dioxane-4,6-dione)

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Lin Chunhua, Yuan Jianjun, Liu Deyong, Zhang Houfu, Xu Zhaohui. Efficient Synthesis of 5,5-(Phenylmethylene)bis(2,2-dimethyl-1,3-dioxane-4,6-dione) Derivatives in Biobased Gluconic Acid Aqueous Solution[J]. Chin. J. Org. Chem., 2017, 37(6): 1560-1564.

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生物介质葡萄糖酸水溶液中5，5-（苯基亚甲基）双（2，2-二甲基二噁烷-4，6-二酮）衍生物的有效合成

Efficient Synthesis of 5,5-(Phenylmethylene)bis(2,2-dimethyl-1,3-dioxane-4,6-dione) Derivatives in Biobased Gluconic Acid Aqueous Solution

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