Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (8): 1964-1977.DOI: 10.6023/cjoc201702002 Previous Articles     Next Articles



赵邦屯a, 陶晶晶b, 陈小纪b, 朱卫民b   

  1. a 洛阳师范学院化学化工学院 洛阳 471934;
    b 郑州大学化学与分子工程学院 郑州 450010
  • 收稿日期:2017-02-03 修回日期:2017-04-07 发布日期:2017-04-27
  • 通讯作者: 赵邦屯, 朱卫民;
  • 基金资助:


Progress on Synthesis and Application of Triazole-Based Tetrathiafulvalene Derivatives

Zhao Bangtuna, Tao Jingjingb, Chen Xiaojib, Zhu Weiminb   

  1. a College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934;
    b College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001
  • Received:2017-02-03 Revised:2017-04-07 Published:2017-04-27
  • Contact: 10.6023/cjoc201702002;
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21172105).

Tetrathiafulvalene (TTF) is an excellent electron donor, therefore it has been used in amyriad of molecular conductors and supramolecular application. The main focus of this review is on the recent progress of synthesis and application of various triazole-based TTF derivatives (TTFs) mainly including traditional tetrathiafulvalene, tetrathiafulvalene vinylogue and extended tetrathiafulvalene via click chemistry. Assisting copper(I)-catalyzed azide-alkyne cycloaddition reaction (CuAAC), the general aspects of TTF molecular design are mainly involved in the reactions of terminal propargyl TTFs with terminal azided substrates as well as the reactions of terminal azided TTFs with terminal propargyl various substrates. This survey is also presented from the view of supramolecular application of the triazole-based TTF systems in molecular recognition, molecular assembly as well as molecular photoelectric and photovoltaic functional materials etc.

Key words: click reaction, triazole, tetrathiafulvalene, photoelectric functional material