Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (10): 3279-3288.DOI: 10.6023/cjoc202004022 Previous Articles     Next Articles


郝冰洁a,b,c, 宋涛a, 黄晓宇b,c, 叶茂a, 钱文昊a   

  1. a 上海市徐汇区牙病防治所 上海 200032;
    b 上海科技大学物质科学与技术学院 上海 201210;
    c 中国科学院上海有机化学研究所 上海 200032
  • 收稿日期:2020-04-14 修回日期:2020-05-04 发布日期:2020-05-11
  • 通讯作者: 黄晓宇, 钱文昊;
  • 基金资助:

Organic Reactions in Covalent Functionalization of Graphene

Hao Bingjiea,b,c, Song Taoa, Huang Xiaoyub,c, Ye Maoa, Qian Wenhaoa   

  1. a Department of Stomatology, Shanghai Xuhui District Dental Center, Shanghai 200032;
    b Shanghaitech University, School of Physical Science and Technology, Shanghai 201210;
    c Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Shanghai 200032
  • Received:2020-04-14 Revised:2020-05-04 Published:2020-05-11
  • Supported by:
    Project supported by the National Natural Science Foundation of China (No. 51773222), the Shanghai Scientific and Technological Innovation Project (No. 20ZR1452200), the Scientific Research Project of Science and Technology Commission of Xuhui Municipality (No. SHXH201613), the Scientific Research Project of Xuhui Provincial Commission of Health and Family Planning (No. SHXH201706), the Program for Outstanding Medical Academic Leader (No. 2019LJ27) and the Shanghai Medical Key Specialty (No. ZK2019B12).

Graphene and graphene oxide possess unique structure and excellent properties, and have become popular potential materials in biology, information, energy and other fields in recent years. The high-quality nanocomposites were obtained by hybridizing graphene-based materials with functional molecules, polymers and nanoparticles. Besides the modification via weak interaction, covalent modification of graphene and graphene oxide via organic reaction can stably and effectively optimize the structure, enhance their performances and extend their applications. In this review, the diverse approaches of chemically covalent modification of graphene and graphene oxide are reviewed via esterification, acylation, Williamson reaction, Eschenmoser-Claisen[3,3] σ rearrangement and click chemistry, and the future development trend is prospected.

Key words: graphene, graphene oxide, covalent functionalization, organic reactions