静电纺丝技术制备Tb(BA)3phen/PANI/PVP光电双功能复合纳米纤维

doi:10.6023/A1201151

化学学报 ›› 2012, Vol. 70 ›› Issue (14): 1576-1582.DOI: 10.6023/A1201151 上一篇

研究论文

静电纺丝技术制备Tb(BA)₃phen/PANI/PVP光电双功能复合纳米纤维

王莹熇, 王进贤, 董相廷, 于文生, 刘桂霞

长春理工大学应用化学与纳米技术吉林省高校重点实验室长春 130022

投稿日期:2012-01-15 发布日期:2012-05-18
通讯作者: 董相廷
基金资助:
项目受国家自然科学基金(Nos. 50972020, 51072026);教育部博士点基金(Nos. 20102216110002, 20112216120003);吉林省科技发展计划重大项目(Nos. 20070402, 20060504);教育部科学技术研究重点项目(No. 207026)资助.

Electrospinning Fabrication of Tb(BA)₃phen/PANI/PVP Luminescence-Electricity Bifunctional Composite Nanofibers

Wang Yinghe, Wang Jinxian, Dong Xiangting, Yu Wensheng, Liu Guixia

Key Laboratory of Applied Chemistry and Nanotechnology at Universities of Jilin Province, Changchun University of Science and Technology, Changchun 130022

Received:2012-01-15 Published:2012-05-18
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 50972020, 51072026), Ph.D. Programs Foundation of the Ministry of Education of China (Nos. 20102216110002, 20112216120003), the Science and Technology Development Planning Project of Jilin Province (Nos. 20070402, 20060504), Key Research Project of Science and Technology of Ministry of Education of China (No. 207026).

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摘要/Abstract

采用静电纺丝技术将聚苯胺(PANI)和稀土配合物[Tb(BA)₃phen]掺杂到高分子材料(PVP)中, 制备出一类新型的具有光电双功能的Tb(BA)₃phen/PANI/PVP复合纳米纤维. 用扫描电子显微镜(SEM)、X射线能量色散谱仪(EDS)、荧光光谱仪及宽频介电松弛谱仪对样品进行了表征. 结果表明, 复合纳米纤维直径为(331±43) nm. 在 276 nm紫外光激发下, Tb(BA)₃phen/PANI/PVP复合纳米纤维发射出主峰位于491, 547和585 nm的绿光, 对应Tb³⁺的⁵D₄→⁷F₆, ⁵D₄→⁷F₅和⁵D₄→⁷F₄跃迁. 当Tb(BA)₃phen:PANI:PVP的质量比为15:10:100时, 复合纳米纤维的荧光发射最强, 其电导率随PANI含量的增大而升高, 在PANI:PVP为50% (wt%)时, 其电导率在高频(10⁶ Hz)下达1.531×10^-6 S/cm.

关键词: 静电纺丝技术, Tb(BA)₃phen/PANI/PVP, 纳米纤维, 聚苯胺

A new kind of luminescence-electricity bifunctional Tb(BA)₃phen/PANI/PVP composite nanofibers was fabricated through doping of polyaniline (PANI) and terbium complex [Tb(BA)₃phen] in polyvinyl pyrrolidone (PVP) via electrospinning. Scanning electron microscope (SEM), energy dispersive spectrometer (EDS), fluorescence spectrometer and broadband dielectric spectrometer were used to characterize the samples. The results indicated that the average diameter of the Tb(BA)₃phen/PANI/PVP composite nanofibers was ca. (331±43) nm. Under the excitation of 276 nm ultraviolet, Tb(BA)₃phen/PANI/PVP composite nanofibers emitted the predominant emission peaks at 491, 547 and 585 nm, corresponding to ⁵D₄→⁷F₆, ⁵D₄→⁷F₅ and ⁵D₄→⁷F₄ transitions of Tb³⁺, respectively. The strongest emission intensity was acquired when the mass ratios of Tb(BA)₃phen, PANI and PVP was 15:10:100. The electric conductivity of the composite nanofibers was increased with the increase of PANI content, and reached 1.531×10^-⁶ S/cm in high frequency electric field (10⁶ Hz) when the mass ratio of PANI to PVP was 50%. The luminescent intensity and electric conductivity of Tb(BA)₃phen/ PANI/PVP composite nanofibers can be tuned via adding of various amounts of Tb(BA)₃phen and PANI into the composite nanofibers. This preparative technique is of universal significance and can be used to fabricate other similar bifunctional luminescence-electricity composite nanofibers. This new type bifunctional luminescence-electricity composite nanofibers will have wide applications in many fields due to their excellent fluorescence and conductivity.

Key words: electrospinning, Tb(BA)₃phen/PANI/PVP, nanofiber, polyaniline

引用此文

王莹熇, 王进贤, 董相廷, 于文生, 刘桂霞. 静电纺丝技术制备Tb(BA)₃phen/PANI/PVP光电双功能复合纳米纤维[J]. 化学学报, 2012, 70(14): 1576-1582.

Wang Yinghe, Wang Jinxian, Dong Xiangting, Yu Wensheng, Liu Guixia. Electrospinning Fabrication of Tb(BA)₃phen/PANI/PVP Luminescence-Electricity Bifunctional Composite Nanofibers[J]. Acta Chimica Sinica, 2012, 70(14): 1576-1582.

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静电纺丝技术制备Tb(BA)₃phen/PANI/PVP光电双功能复合纳米纤维

Electrospinning Fabrication of Tb(BA)₃phen/PANI/PVP Luminescence-Electricity Bifunctional Composite Nanofibers

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