In3+共掺杂诱导NaY0.95-xYb0.03Er0.02F4相转变与上转换发光增强研究

doi:10.6023/A13070794

化学学报 ›› 2013, Vol. 71 ›› Issue (12): 1639-1646.DOI: 10.6023/A13070794 上一篇下一篇

研究论文

In³⁺共掺杂诱导NaY_0.95_-_xYb_0.03Er_0.02F₄相转变与上转换发光增强研究

俞瀚^a, 黄清明^a,b, 曹文兵^a, 张新奇^b, 俞建长^a

a 福州大学材料科学与工程学院福州 350108;
b 福州大学测试中心福州 350002

投稿日期:2013-07-27 发布日期:2013-10-12
通讯作者: 俞瀚 E-mail:fjfzyh@fzu.edu.cn
基金资助:
项目受福建省自然科学基金（No. 2013J05027）与福建省中青年教师教育科研项目（No. JA13050）资助.

Phase Transition Induction and Upconversion Luminescence Enhancement of NaY_0.95_-_x Yb_0.03Er_0.02F₄ by In³⁺ Codoping

Yu Han^a, Huang Qingming^a,b, Cao Wenbing^a, Zhang Xinqi^b, Yu Jianchang^a

a College of Materials Science and Engineering, Fuzhou University, Fuzhou 350108;
b Instrumental Analysis & Measurement Center, Fuzhou University, Fuzhou 350002

Received:2013-07-27 Published:2013-10-12
Supported by:
Project supported by the Fujian Province Natural Science Fund (No. 2013J05027) and the Fujian Province Education-Science Project for Middle-aged and Young Teachers (No. JA13050)

文章分享

1. In³⁺共掺杂诱导NaY_0.95_-_xYb_0.03Er_0.02F₄相转变与上转换发光增强研究.PDF(821KB)

摘要/Abstract

引入In³⁺作为新的掺杂离子通过水热法合成了In³⁺与Er³⁺，Yb³⁺共掺杂的NaYF₄上转换发光材料. 通过XRD表征及Rietveld精修，SEM以及TEM研究了In掺杂引起的NaYF₄形貌与晶体结构的变化. 通过发射光谱与发光衰减曲线表征了掺杂NaYF₄的上转换发光性能，以研究晶体微观结构与上转换发光性能之间的关系. 结果表明随着In掺杂量的增加，立方相NaYF₄的晶格畸变不断增强且发生由立方相向六方相的转变. 对于六方相NaYF₄，其上转换发光强度随着In含量的提高不断增强并当In含量为3%时达到最大值. 该研究结果可以有助于设计与合成具有优良上转换发光性能的材料.

关键词: 上转换, In³⁺掺杂, 相转变, 发光, 氟钇酸钠

In³⁺ was taken as a new dopant to codope NaYF₄ with Er³⁺ and Yb³⁺ by hydrothermal synthesis in this manuscript. How to improve phase transition of NaYF₄ from cubic to hexagonal and how to improve upconversion luminescence performance of hexagonal NaYF₄ are both important problems because hexagonal NaYF₄ is the most efficient matrix material for upconversion. Considering these two problems, we report the study of crystal structure and upconversion emission of In³⁺-codoped NaYF₄ to discover phase transition mechanism and upconversion luminescence properties changed with different In³⁺ codoping concentration. NaY_0.92Yb_0.03Er_0.02F₄ was tridoped with 0, 2, 4, 6, 8 and 10 mol% In³⁺ at 170 ℃ for 8 h in order to study phase transition of NaYF₄. The other group of samples was prepared by the same procedure except In³⁺codoping concentration was replaced as 0, 1, 2, 3, 4 and 5 mol% and the reaction proceeded at 190 ℃ for 12 h in order to obtain pure hexagonal NaYF₄for study of its upconversion luminescence. The change of morphologies and crystal structural transition caused by In³⁺ codoping was explored by XRD, Rietveld refinement, SEM and TEM analysis methods, while the upconversion luminescence was characterized by emission spectra and luminescence decay curves, for the relationship between crystal microstructure and luminescence properties to be discussed in our investigation. On the basis of these characterizations we found that with rising of the In³⁺ codoping concentration, the phase transition of NaYF₄ from cubic to hexagonal was improved. The intensity of upconversion luminescence was also found to be increased to the maximum when 3 mol% In³⁺ was codoped into hexagonal NaYF₄. The analysis and discussion discovered that the phase transition of NaYF₄ was correlated with the lattice distortion of cubic NaYF₄ improved by In³⁺ codoping. The intensity of upconversion luminescence was proved to be increased by the asymmetry of the local crystal field changed with the In³⁺ codoping concentration. This investigation may be helpful for design and synthesis of other functional materials.

Key words: upconversion, In³⁺ codoping, phase transition, luminescence, NaYF₄

引用此文

俞瀚, 黄清明, 曹文兵, 张新奇, 俞建长. In³⁺共掺杂诱导NaY_0.95_-_xYb_0.03Er_0.02F₄相转变与上转换发光增强研究[J]. 化学学报, 2013, 71(12): 1639-1646.

Yu Han, Huang Qingming, Cao Wenbing, Zhang Xinqi, Yu Jianchang. Phase Transition Induction and Upconversion Luminescence Enhancement of NaY_0.95_-_x Yb_0.03Er_0.02F₄ by In³⁺ Codoping[J]. Acta Chimica Sinica, 2013, 71(12): 1639-1646.

导出引用 EndNote|Reference Manager|ProCite|BibTeX|RefWorks

分享此文

参考文献

[1] Wang, F.; Liu, X. G. Chem. Soc. Rev. 2009, 38, 976.

[2] Heer, S.; Kompe, K.; Gudel, H. U.; Haase, M. Adv. Mater. 2004, 16, 2102.

[3] Vennerberg, D.; Lin, Z. Q. Sci. Adv. Mater. 2011, 3, 26.

[4] Chen, W. J. Nanosci. Nanotechnol. 2008, 8, 1019.

[5] Wang, M.; Mi, C. C.; Zhang, Y. X.; Liu, J. L.; Li, F.; Mao, C. B.; Xu, S. K. J. Phys. Chem. C 2009, 113, 19021.

[6] Ryu, J.; Park, H. Y.; Kim, K.; Kim, H.; Yoo, J. H.; Kang, M.; Im, K.; Grailhe, R.; Song, R. J. Phys. Chem. C 2010, 114, 21077.

[7] Nagarajan, S.; Zhang, Y. Nanotechnology 2011, 22, 395101.

[8] Chen, F.; Bu, W. B.; Zhang, S. J.; Liu, J. N.; Fan, W. P.; Zhou, L. P.; Peng, W. J.; Shi, J. L. Adv. Funct. Mater. 2013, 23, 298.

[9] Righini, G. C.; Ferrari, M. Riv. Nuovo. Cimento. 2005, 28, 1.

[10] Zhou, S. S.; Deng, K. M.; Wei, X. T.; Jiang, G. C.; Duan, C. K.; Chen, Y. H.; Yin, M. Opt. Commun. 2013, 291, 138.

[11] Vetrone, F.; Naccache, R.; Zamarron, A.; de la Fuente, A. J.; Sanz-Rodriguez, F.; Maestro, L. M.; Rodriguez, E. M.; Jaque, D.; Sole, J. G.; Capobianco, J. A. ACS Nano 2010, 4, 3254.

[12] Li, T. G.; Liu, S. W.; Zhang, H. P.; Wang, E. H.; Song, L. J.; Wang, P. J. Mater. Sci. 2011, 46, 2882.

[13] van der Ende, B. M.; Aarts, L.; Meijerink, A. Phys. Chem. Chem. Phys. 2009, 11, 11081.

[14] Wang, F.; Deng, R. R.; Wang, J.; Wang, Q. X.; Han, Y.; Zhu, H. M.; Chen, X. Y.; Liu, X. G. Nat. Mater. 2011, 10, 968.

[15] Li, Z. Q.; Li, X. D.; Liu, Q. Q.; Chen, X. H.; Sun, Z.; Liu, C.; Ye, X. J.; Huang, S. M. Nanotechnology 2012, 23, 345606.

[16] Zhang, J.; Shen, H. O.; Guo, W.; Wang, S. H.; Zhu, C. T.; Xue, F.; Hou, J. F.; Su, H. Q.; Yuan, Z. B. J. Power Sources 2013, 226, 47.

[17] Suyver, J. F.; Aebischer, A.; Biner, D.; Gerner, P.; Grimm, J.; Heer, S.; Kramer, K. W.; Reinhard, C.; Gudel, H. U. Opt. Mater. 2005, 27, 1111.

[18] Liang, X.; Wang, X.; Zhuang, J.; Peng, Q.; Li, Y. D. Adv. Funct. Mater. 2007, 17, 2757.

[19] Wang, L. Y.; Li, P.; Li, Y. D. Adv. Mater. 2007, 19, 3304.

[20] Mai, H. X.; Zhang, Y. W.; Si, R.; Yan, Z. G.; Sun, L. D.; You, L. P.; Yan, C. H. J. Am. Chem. Soc. 2006, 128, 6426.

[21] Mai, H. X.; Zhang, Y. W.; Sun, L. D.; Yan, C. H. J. Phys. Chem. C 2007, 111, 13721.

[22] Mai, H. X.; Zhang, Y. W.; Sun, L. D.; Yan, C. H. J. Phys. Chem. C 2007, 111, 13730.

[23] Li, C. X.; Quan, Z. W.; Yang, P. P.; Yang, J.; Lian, H. Z.; Lin, J. J. Mater. Chem. 2008, 18, 1353.

[24] Huang, Q. M.; Yu, H.; Zhang, X. Q.; Yu, J. C. Acta Chim. Sinica 2013, 71, 1071 (黄清明, 俞瀚, 张新奇, 俞建长, 化学学报, 2013, 71, 1071).

[25] Chen, J.; Guo, C. R.; Wang, M.; Huang, L.; Wang, L. P.; Mi, C. C.; Li, J.; Fang, X. X.; Mao, C. B.; Xu, S. K. J. Mater. Chem. 2011, 21, 2632.

[26] Wang, F.; Liu, X. G. J. Am. Chem. Soc. 2008, 130, 5642.

[27] Auzel, F. Chem. Rev. 2004, 104, 139.

[28] Chen, D. Q.; Yu, Y. L.; Huang, F.; Huang, P.; Yang, A. P.; Wang, Y. S. J. Am. Chem. Soc. 2010, 132, 9976.

[29] Huang, Q.; Yu, J.; Ma, E.; Lin, K. J. Phys. Chem. C 2010, 114, 4719.

[30] Judd, B. R. Phys. Rev. 1962, 127, 750.

[31] Ofelt, G. S. J. Chem. Phys. 1962, 37, 511.

[32] Dou, Q. Q.; Zhang, Y. Langmuir 2011, 27, 13236.

[33] Lifshitz, I. M.; Slyozov, V. V. J. Phys. Chem. Solids 1961, 19, 35.

In³⁺共掺杂诱导NaY_0.95_-_xYb_0.03Er_0.02F₄相转变与上转换发光增强研究

Phase Transition Induction and Upconversion Luminescence Enhancement of NaY_0.95_-_x Yb_0.03Er_0.02F₄ by In³⁺ Codoping

PDF

补充材料

可视化

摘要/Abstract

引用此文

分享此文

参考文献

相关文章 15

编辑推荐

相关统计

本文评价

[1]	史雨晴, 储名珠, 韩波, 马豪杰, 李然, 侯雪艳, 张玉琦, 王记江. 智能二维光子晶体水凝胶精准检测Hg²⁺[J]. 化学学报, 2024, 82(1): 9-15.
[2]	王一诺, 邵世洋, 王利祥. 窄谱带多重共振有机高分子荧光材料研究进展^★[J]. 化学学报, 2023, 81(9): 1202-1214.
[3]	葛凤洁, 张开志, 曹清鹏, 徐慧, 周涛, 张文浩, 班鑫鑫, 张晓波, 李娜, 朱鹏. 柔性芴基嵌段型延迟荧光二聚体的设计、合成及电致发光性能[J]. 化学学报, 2023, 81(9): 1157-1166.
[4]	陶鹏, 郑小康, 王国良, 盛星浩, 姜贺, 李文桃, 靳继彪, 王瑞鸿, 苗艳勤, 王华, 黄维扬. 新型双极传输特性橙光铱(III)配合物的设计、合成及其电致发光^★[J]. 化学学报, 2023, 81(8): 891-897.
[5]	任妍妍, 李欣, 韩英锋. 基于氮杂环卡宾蓝光有机自由基的合成及其光学性质研究^★[J]. 化学学报, 2023, 81(7): 735-740.
[6]	陈慧敏, 王龙, 张盼, 白西林, 周国君. 高效率Tb^3＋单掺绿色荧光粉的光致/应力发光研究[J]. 化学学报, 2023, 81(7): 771-776.
[7]	刘振宇, 饶俊峰, 祝守加, 王兵洋, 余帆, 冯全友, 解令海. 溶液加工型自主体热活化延迟荧光材料的研究进展[J]. 化学学报, 2023, 81(7): 820-835.
[8]	王银凤, 李猛, 陈传峰. 基于手性三蝶烯的红光热激活延迟荧光聚合物及其有机发光二极管研究^★[J]. 化学学报, 2023, 81(6): 588-594.
[9]	张少秦, 李美清, 周中军, 曲泽星. 多共振热激活延迟荧光过程的理论研究[J]. 化学学报, 2023, 81(2): 124-130.
[10]	温哥华, 温都日娜, 陈秀梅, 麻秀芳, 翁果果, 韦依凡, 鲍松松, 谢小吉, 胡淑贤, 郑丽敏. 层状铀酰膦酸配位聚合物作为双响应光致发光温度计^★[J]. 化学学报, 2023, 81(10): 1311-1317.
[11]	李奎琛, 郑开元, 何静嘉, 金泽浩, 何秋, 王丽丽. 单相硫化锌量子点制作白光发光二极管(WQLEDs)[J]. 化学学报, 2023, 81(10): 1327-1333.
[12]	贾亚辉, 李春生, 徐忠震, 刘伟, 高道伟, 陈国柱. 载体相变下Pt-TiO₂ SMSI研究及其对CO催化性能的影响[J]. 化学学报, 2022, 80(9): 1289-1298.
[13]	贾彦荣, 高贯雷, 夏敏. 调控有机小分子晶体力致发光行为的方法[J]. 化学学报, 2022, 80(9): 1309-1321.
[14]	刘斌, 陈磅宽. 基于联萘酚骨架的新型圆偏振发光材料的合成及性能探究[J]. 化学学报, 2022, 80(7): 929-935.
[15]	贺续发, 贾康乐, 余龙飞, 刘明杰, 郑小珊, 李欢玲, 辛锦兰, 黄淋佳. 马来松香酸和纳米氧化铝颗粒协同稳定具有pH响应性的Pickering乳液[J]. 化学学报, 2022, 80(6): 765-771.