异质结界面修饰对TiO2/P3HT杂化太阳电池光电性能的增强作用

doi:10.6023/A14110783

化学学报 ›› 2014, Vol. 72 ›› Issue (12): 1245-1250.DOI: 10.6023/A14110783 上一篇

研究论文

异质结界面修饰对TiO₂/P3HT杂化太阳电池光电性能的增强作用

裴娟^a, 郝彦忠^a, 吕海军^b, 孙宝^a, 李英品^a, 王尚鑫^a

a. 河北科技大学理学院石家庄 050018;
b. 河北科技大学化学与制药工程学院石家庄 050018

投稿日期:2014-11-14 发布日期:2014-11-18
通讯作者: 郝彦忠 E-mail:yzhao@hebust.edu.cn
基金资助:
项目受国家自然科学基金(No.21173065),河北省自然科学基金(Nos.B2014208062,B2014208066,B2014208121),河北省科技计划项目(No.13214413),河北科技大学博士启动基金(Nos.QD201050,010087)资助.

Improving the Photovoltaic Performance of TiO₂/P3HT Hybrid Solar Cell by Interfacial Modification

Pei Juan^a, Hao Yanzhong^a, Lv Haijun^b, Sun Bao^a, Li Yingpin^a, Wang Shangxin^a

a. College of Sciences, Hebei University of Science and Technology, Shijiazhuang 050018;
b. School of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018

Received:2014-11-14 Published:2014-11-18
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21173065), Natural Science Foundation of Hebei Province of China (Nos. B2014208062, B2014208066, B2014208121), Science and Technology Project of Hebei Province, China (No. 13214413). the Doctoral Starting up Foundation (Nos. QD201050, 010087) of Hebei University of Science and Technology, China.

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摘要/Abstract

采用水热法在F-SnO₂(FTO)导电玻璃上制备了一维TiO₂纳米棒阵列, 将一种两亲有机三苯胺染料M分子吸附在其表面, 进而旋涂有机聚合物聚3-己基噻吩P3HT, 构建结构为FTO/TiO₂/M/P3HT/PEDOT:PSS/Au的杂化太阳电池. 瞬态光电流谱反映在杂化电极中存在pn异质结. 接触角测试表明TiO₂表面吸附有机M分子后, 亲水性表面转变为疏水性表面, 利于与聚合物P3HT的进一步接触; 稳态荧光发射光谱表明经修饰的杂化电极的荧光发射强度降低, 由荧光衰减曲线拟合得到的荧光寿命降低, 说明在TiO₂与P3HT之间存在有效的电荷转移, 电荷复合被抑制. 电化学阻抗分析表明界面修饰后电子复合电阻和电子寿命增大. 电池的特性参数均比界面修饰前有所提高, 光电转换效率为1.61%. 另外, 对该电池的工作机理、电荷传输过程进行了初步探讨.

关键词: 杂化太阳电池, 界面修饰, 激子分离效率, 电荷复合, 光电性能

In this paper, highly ordered and vertically oriented one-dimensional TiO₂ nanorod arrays were prepared firstly on F-SnO₂ (FTO) conductive glass by hydrothermal method, then an amphiphilic organic triphenylamine-type dye 2-(5-(4- (diphenylamino)benzylidene)-4-oxo-2-thioxothiazolidin-3-yl)acetic acid (M for short) was adsorbed on its surface. After spin-coating organic polymer poly(3-hexylthiophene) (P3HT for short), we fabricated the modified hybrid solar cell device with the structure of FTO/TiO₂/M/P3HT/PEDOT:PSS/Au. The transient photocurrent of the electrodes reflects the pn heterojunction is existent indeed in the hybrid electrode. The contact angle changes from 13.9° for pure TiO₂ to 112.6° for M-modified sample. This hydrophobic surface facilitates TiO₂ further contacting with polymer P3HT. The steady state photoluminescence (PL) emission spectra shows stronger quenching of PL intensity, and PL lifetime fitted from the PL decay curves decreased for the M-modified hybrid film. These conclusions implie the effective charge transfer between P3HT and TiO₂, which could suppress the charge recombination. Electrochemical impedance analysis showed that the electron recombination resistance and electron lifetime were increased after interfacial modification. The photovoltaic performance of the modified hybrid cell along with the unmodified one was tested. The open-circuit voltage (V_oc), short-circuit current (J_sc), fill factor (FF) are increased for the modified device, and resulting the power conversion efficiency (η) of 1.61%. In addition, the mechanism of the cell and the charge transfer process were investigated preliminarily. The interfacial modifier might be functioned as a "bridge" to transfer electrons to inorganic semiconductor, and transfer holes to polymer also. The modifier could possibly mediate charge transfer in one direction from P3HT to TiO₂ for electron accepting and result in more efficient charge separation due to the cascaded energy levels. This work may provide a useful method for increasing the performance of hybrid solar cells by interface modification.

Key words: hybrid solar cell, heterojunction interface modification, exciton dissociation efficiency, charge recombination, photovoltaic performance

引用此文

裴娟, 郝彦忠, 吕海军, 孙宝, 李英品, 王尚鑫. 异质结界面修饰对TiO₂/P3HT杂化太阳电池光电性能的增强作用[J]. 化学学报, 2014, 72(12): 1245-1250.

Pei Juan, Hao Yanzhong, Lv Haijun, Sun Bao, Li Yingpin, Wang Shangxin. Improving the Photovoltaic Performance of TiO₂/P3HT Hybrid Solar Cell by Interfacial Modification[J]. Acta Chimica Sinica, 2014, 72(12): 1245-1250.

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参考文献

[1] Green, M. A. Physica E 2002, 14, 11.
[2] Hao, Y.-Z.; Fan, L.-X.; Sun, B.; Sun, S.; Pei, J. Acta Chim. Sinica 2014, 72, 114. (郝彦忠, 范龙雪, 孙宝, 孙硕, 裴娟, 化学学报, 2014, 72, 114.)
[3] Zhou, Y. F.; Eck, M.; Krüger, M. Energy Environ. Sci. 2010, 3, 1851.
[4] Hao, Y.-Z.; Cao, Y.-H.; Sun, B.; Zhang, Y.-H.; Li, Y.-P.; Xu, D.-S.; Li, X.-L. Acta Chim. Sinica 2012, 70, 1139. (郝彦忠, 曹寅虎, 孙宝, 张彦辉, 李英品, 徐东升, 李香玲, 化学学报, 2012, 70, 1139.)
[5] Pei, J.; Hao, Y. -Z.; Sun, B.; Li, Y.-P.; Fan, L.-X.; Sun, S.; Wang, S.-X. Acta Phys. -Chim. Sin. 2014, 30, 397. (裴娟, 郝彦忠, 孙宝, 李英品, 范龙雪, 孙硕, 王尚鑫, 物理化学学报, 2014, 30, 397.)
[6] Liu, J. C.;Wang, W. L.; Yu, H. Z.; Wu, Z. L.; Peng, J. B.; Cao, Y. Sol. Energy Mater. Sol. Cells 2008, 92, 1403.
[7] Park, I.; Lim, Y.; Noh, S.; Lee, D.; Meister, M.; Amsden, J. J.; Laquai, F.; Lee, C.; Yoon, D. Y. Org. Electron. 2011, 12, 424.
[8] Celik, D.; Krueger, M.; Veit, C.; Schleiermacher, H. F.; Zimmermann, B.; Allard, S.; Dumsch, I.; Scherf, U.; Rauscher, F.; Niyamakom, P. Sol. Energy Mater. Sol. Cells 2012, 98, 433.
[9] Goh, C.; Scully, S. R.; McGehee, M. D. J. Appl. Phys. 2007, 101, 114503.
[10] Zhang,W.; Zhu, R.; Liu, B.; Ramakrishna, S. Appl. Energy 2012, 90, 305.
[11] Liao,W. P.; Hsu, S. C.; Lin,W. H.;Wu, J. J. J. Phys. Chem. C 2012, 116, 15938.
[12] Wang, M. Q.;Wang, X. G. Sol. Energy Mater. Sol. Cells 2008, 92, 766.
[13] Liu, J. S.; Tanaka, T.; Sivula, K.; Alivisatos, A. P.; Fréchet, J. M. J. J. Am. Chem. Soc. 2004, 126, 6550.
[14] Querner, C.; Benedetto, A.; Demadrille, R.; Rannou, P.; Reiss, P. Chem. Mater. 2006, 18, 4817.
[15] Bhongale, C. J.; Thelakkat, M. Sol. Energy Mater. Sol. Cells 2010, 94, 817.
[16] Li, Y.-P.; Hao, Y.-Z.; Sun, S.; Sun, B.; Pei, J.; Zhang, Y.-H.; Xu, D.-S.; Liu, L. RSC Adv. 2013, 3, 1541.
[17] Hao, Y.-Z.; Luo, C.; Sun, B.; Sun, S.; Li, Y.-P.; Shen, S.-G.; Xu, D.-S. Sci. China Chem. 2013, 56, 755.
[18] Liang, M.; Xu, W.; Cai, F.-S.; Chen, P.-Q.; Peng, B.; Chen, J.; Li, Z.-M. J. Phys. Chem. C 2007, 111, 4465.
[19] Freitas, F. S.; Clifford, J. N.; Palomares, E.; Nogueira, A. F. Phys. Chem. Chem. Phys. 2012, 14, 11990.
[20] Zhong, M.; Yang, D.; Zhang, J.; Shi, J. Y.; Wang, X. L.; Li, C. Sol. Energy Mater. Sol. Cells 2012, 96, 160.
[21] Liang, Y. L.; Peng, B.; Chen, J. J. Phys. Chem. C 2010, 114, 10992.
[22] Wang, Q.; Moser, J.; Grätzel, M. J. Phys. Chem. B 2005, 109, 14945.

异质结界面修饰对TiO₂/P3HT杂化太阳电池光电性能的增强作用

Improving the Photovoltaic Performance of TiO₂/P3HT Hybrid Solar Cell by Interfacial Modification

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