金属-有机骨架材料在色谱分离中的应用

doi:10.6023/A16090482

摘要/Abstract

金属-有机骨架材料（Metal-organic frameworks，MOFs），因其具有较好的热稳定性、化学稳定性、可设计性等特点，广泛应用于气体吸附、物质分离、提纯、催化等领域，同时也作为模板制备各种功能材料.MOFs作为色谱分离的材料已得到了较多的研究与应用.按照被分离物质的类别，综述和总结了不同MOFs材料作为色谱固定相的分离效果，重点介绍了MOFs材料的色谱分离机理.MOFs材料的孔径、功能基团和不饱和金属位点在分离中起到重要的作用，最后对MOFs在色谱分离应用中的问题和前景进行了分析和展望.

关键词: 金属-有机骨架材料, 气相色谱, 高效液相色谱, 色谱分离, 色谱柱

Metal-organic frameworks (MOFs) are synthesized via the self-assembling combination of organic ligands and inorganic metals or metal-oxo units (secondary building units,SBUs) using strong bonds to form a porous open crystalline.Because of their outstanding thermal stability,chemical stability and designability,MOFs are successfully applied in various fields,such as gas absorption,separation,purification,catalysis,as well as templates for various functional materials.MOFs are also used as column materials for gas or liquid chromatography separation.In this paper,the studies about MOFs used as stationary phases in gas chromatography and high-performance liquid chromatography were reviewed according to the separated various analytes.We summarized the separation effects of different MOFs for different substances,especially focusing on the separation mechanism of MOFs.The key influence factors on the chromatographic separation,such as pore diameter,functional groups and unsaturated metal sites of MOFs,were expounded.Then,the challenges of MOFs as stationary phases in gas and high-performance liquid chromatography were discussed,which include the mechanism,chiral separation,the limited MOFs in chromatographic separation.The future research in this field should focus on defining separation mechanism,improving their stability and synthesizing the MOFs with special function.

Key words: MOFs, gas chromatography, high-performance liquid chromatography, chromatographic separation, chromatographic column

引用此文

李晓新, 束伦, 陈莎. 金属-有机骨架材料在色谱分离中的应用[J]. 化学学报, 2016, 74(12): 969-979.

Li Xiaoxin, Shu Lun, Chen Sha. Application of Metal-Organic Frameworks in Chromatographic Separation[J]. Acta Chim. Sinica, 2016, 74(12): 969-979.

导出引用 EndNote|Reference Manager|ProCite|BibTeX|RefWorks

分享此文

参考文献

[1] Furukawa, H.; Cordova, K. E.; O'Keeffe, M.; Yaghi, O. M. Science 2013, 341, 974.
[2] Férey, G. From Zeolites to Porous MOF Materials:the 40th Anniversary of International Zeolite Conference, Proceedings of the 15th in International Zeolite Conference, Eds.:Xu, R.; Gao, Z.; Chen, J., Elsevier, Beijing, 2007, pp. 66~84.
[3] Férey, G. Chem. Soc. Rev. 2008, 37, 191.
[4] Yusuf, K.; Aqel, A.; Alothman, Z. J. Chromatogr. A 2014, 1348, 1.
[5] Sabouni, R.; Kazemian, H.; Rohani, S. Environ. Sci. Pollut. Res. 2014, 21, 5427.
[6] Rosi, N. L.; Eckert, J.; Eddaoudi, M.; Vodak, D. T.; Kim, J.; O'Keeffe, M.; Yaghi, O. M. Science 2003, 300, 1127.
[7] Li, J.; Sculley, J.; Zhou, H. Chem. Rev. 2012, 112, 869.
[8] Van de Voorde, B.; Bueken, B.; Denayer, J.; De Vos, D. Chem. Soc. Rev. 2014, 43, 5766.
[9] Czaja, A. U.; Trukhan, N.; Mueller, U. Chem. Soc. Rev. 200938, 1284.
[10] Huang, G.; Chen, Y. Z.; Jiang, H. L. Acta Chim. Sinica 2016, 74, 113. (黄刚, 陈玉贞, 江海龙, 化学学报, 2016, 74, 113.)
[11] Hong, D.; Hwang, Y. K.; Serre, C.; Ferey, G.; Chang, J. S. Adv. Funct. Mater. 2009, 19, 1537.
[12] Li, Y. X.; Zhang, W.; Liu, Z.; Xie, Z. G. Acta Chim. Sinica 2015, 73, 641. (李阳雪, 张巍, 刘智, 谢志刚, 化学学报, 2015, 73, 641.)
[13] Yin, J.; Yang, G.; Wang, H.; Chen, Y. Chem. Commun. 2007, 4614.
[14] Eddaoudi, M.; Kim, J.; Rosi, N.; Vodak, D.; Wachter, J.; O'Keeffe, M.; Yaghi, O. M. Science 2002, 295, 469.
[15] Holcroft, J. M.; Hartlieb, K. J.; Moghadam, P. Z.; Bell, J. G.; Barin, G.; Ferris, D. P.; Bloch, E. D.; Algaradah, M. M.; Nassar, M. S.; Botros, Y. Y.; Thomas, K. M.; Long, J. R.; Snurr, R. Q.; Stoddart, J. F. J. Am. Chem. Soc. 2015, 137, 5706.
[16] Gu, Z.; Yang, C.; Chang, N.; Yan, X. Acc. Chem. Res. 2012, 45, 734.
[17] Yu, Y.; Ren, Y.; Shen, W.; Deng, H.; Gao, Z. TrAC 2013, 50, 33.
[18] Yusuf, K.; Aqel, A.; Alothman, Z. J. Chromatogr. A 2014, 1348, 1.
[19] Yuan, Z. Z.; Luo, F.; Liu, J. L.; Luo, M. B.; Li, F. Q. Chem. Res. Appl. 2013, 25, 614. (袁自遵, 罗峰, 刘建亮, 罗明标, 李芳清, 化学研究与应用, 2013, 25, 614.)
[20] Liu, P.; Tang, L. X.; Lian, Y. H.; Li, Z.; Sun, C. Y.; Chen, G. J. Acta Chim. Sinica 2013, 71, 920. (刘蓓, 唐李兴, 廉源会, 李智, 孙长宇, 陈光进, 化学学报, 2013, 71, 920.)
[21] Chang, N.; Gu, Z.; Wang, H.; Yan, X. Anal. Chem. 2011, 83, 7094.
[22] Luebbers, M. T.; Wu, T.; Shen, L.; Masel, R. I. Langmuir 2010, 26, 15625.
[23] Chen, B.; Liang, C.; Yang, J.; Contreras, D. S.; Clancy, Y. L.; Lobkovsky, E. B.; Yaghi, O. M.; Dai, S. Angew. Chem., Int. Ed. 2006, 45, 1390.
[24] Luebbers, M. T.; Wu, T.; Shen, L.; Masel, R. I. Langmuir 2010, 26, 11319.
[25] Münch, A. S.; Seidel, J.; Obst, A.; Weber, E.; Mertens, F. O. R. L. Chem.-Eur. J. 2011, 17, 10958.
[26] Bozbiyik, B.; Lannoeye, J.; De Vos, D. E.; Baron, G. V.; Denayer, J. F. M. Chem. Phys. 2016, 18, 3294.
[27] Fang, Z.; Zheng, S.; Tan, J.; Cai, S.; Fan, J.; Yan, X.; Zhang, W. J. Chromatogr. A 2013, 1285, 132.
[28] Tian, J.; Lu, C.; He, C.; Lu, T.; Ouyang, G. Talanta 2016, 152, 283.
[29] Chang, N.; Yan, X. J. Chromatogr. A 2012, 1257, 116.
[30] Bozbiyik, B.; Duerinck, T.; Lannoeye, J.; De Vos, D. E.; Baron, G. V.; Denayer, J. F. M. Micropor. Mesopor. Mater. 2014, 183, 143.
[31] Van der Perre, S.; Bozbiyik, B.; Lannoeye, J.; De Vos, D. E.; Baron, G. V.; Denayer, J. F. M. J. Phys. Chem. C 2015, 119, 1832.
[32] Yusuf, K.; Badjah-Hadj-Ahmed, A. Y.; Aqel, A.; Alothman, Z. A. J. Chromatogr. A 2015, 1406, 299.
[33] Srivastava, M.; Roy, P. K.; Ramanan, A. RSC Adv. 2016, 6, 13426.
[34] Muench, A. S.; Mertens, F. O. R. L. J. Mater. Chem. 2012, 22, 10228.
[35] Gu, Z.; Yan, X. Angew. Chem. Int. Ed. 2010, 49, 1477.
[36] Fan, L.; Yan, X. Talanta 2012, 99, 944.
[37] Xie, S.; Zhang, Z.; Wang, Z.; Yuan, L. J. Am. Chem. Soc. 2011, 133, 11892.
[38] Xie, S.; Zhang, X.; Zhang, Z.; Zhang, M.; Jia, J.; Yuan, L. Anal. Bioanal. Chem. 2013, 405, 340.
[39] Xie, S.; Zhang, X.; Zhang, Z.; Yuan, L. Anal. Lett. 2013, 46, 753.
[40] Zhang, X.; Xie, S.; Duan, A.; Wang, B.; Yuan, L. Chromatographia 2013, 76, 831.
[41] Xie, S.; Wang, B.; Zhang, X.; Zhang, J.; Zhang, M.; Yuan, L. Chirality 2014, 26, 27.
[42] Xie, S. M.; Zhang, Z. J.; Yuan, L. M. Chem. J. Chin. Univ. 2014, 35, 1652. (谢生明, 张泽俊, 袁黎明, 高等学校化学学报, 2014, 35, 1652.)
[43] Xie, S.; Zhang, X.; Wang, B.; Zhang, M.; Zhang, J.; Yuan, L. Chromatographia 2014, 77, 1359.
[44] Xue, X.; Zhang, M.; Xie, S.; Yuan, L. Acta Chromatogr. 2015, 27, 15.
[45] Böhle, T.; Mertens, F. Micropor. Mesopor. Mater. 2014, 183, 162.
[46] Finsy, V.; Verelst, H.; Alaerts, L.; De Vos, D.; Jacobs, P. A.; Baron, G. V.; Denayer, J. F. M. J. Am. Chem. Soc. 2008, 130, 7110.
[47] Gu, Z.; Jiang, D.; Wang, H.; Cui, X.; Yan, X. J. Phys. Chem. C 2010, 114, 311.
[48] Münch, A. S.; Mertens, F. O. R. L. CrystEngComm 2015, 17, 438.
[49] Li, Z. Y. Mod. Chem. Ind. 1999, 19, 7. (李政禹, 现代化工, 1999, 19, 7.)
[50] Gu, Z.; Jiang, J.; Yan, X. Anal. Chem. 2011, 83, 5093.
[51] Borjigin, T.; Sun, F.; Zhang, J.; Cai, K.; Ren, H.; Zhu, G. Chem. Commun. (Camb) 2012, 48, 7613.
[52] Sun, J.; Ji, M.; Chen, C.; Wang, W.; Wang, P.; Chen, R.; Zhang, J. Chem. Commun. 2013, 49, 1624.
[53] Maes, M.; Vermoortele, F.; Alaerts, L.; Couck, S.; Kirschhock, C. E. A.; Denayer, J. F. M.; De Vos, D. E. J. Am. Chem. Soc. 2010, 132, 15277.
[54] Yang, C.; Yan, X. Anal. Chem. 2011, 83, 7144.
[55] Zhao, W.; Zhang, C.; Yan, Z.; Bai, L.; Wang, X.; Huang, H.; Zhou, Y.; Xie, Y.; Li, F.; Li, J. J. Chromatogr. A 2014, 1370, 121.
[56] Hartlieb, K. J.; Holcroft, J. M.; Moghadam, P. Z.; Vermeulen, N. A.; Algaradah, M. M.; Nassar, M. S.; Botros, Y. Y.; Snurr, R. Q.; Stoddart, J. F. J. Am. Chem. Soc. 2016, 138, 2292.
[57] Ahmad, R.; Wong-Foy, A. G.; Matzger, A. J. Langmuir 2009, 25, 11977.
[58] Ameloot, R.; Liekens, A.; Alaerts, L.; Maes, M.; Galarneau, A.; Coq, B.; Desmet, G.; Sels, B. F.; Denayer, J. F. M.; De Vos, D. E. Eur. J. Inorg. Chem. 2010, 3735.
[59] Ahmed, A.; Forster, M.; Clowes, R.; Myers, P.; Zhang, H. Chem. Commun. 2014, 50, 14314.
[60] Alaerts, L.; Kirschhock, C. E. A.; Maes, M.; van der Veen, M. A.; Finsy, V.; Depla, A.; Martens, J. A.; Baron, G. V.; Jacobs, P. A.; Denayer, J. E. M.; De Vos, D. E. Angew. Chem. Int. Ed. 2007, 46, 4293.
[61] Yan, Z.; Zhang, W.; Gao, J.; Lin, Y.; Li, J.; Lin, Z.; Zhang, L. RSC Adv. 2015, 5, 40094.
[62] Alaerts, L.; Maes, M.; Giebeler, L.; Jacobs, P. A.; Martens, J. A.; Denayer, J. F. M.; Kirschhock, C. E. A.; De Vos, D. E. J. Am. Chem. Soc. 2008, 130, 14170.
[63] Liu, S.; Yang, C.; Wang, S.; Yan, X. Analyst 2012, 137, 816.
[64] El Osta, R.; Carlin-Sinclair, A.; Guillou, N.; Walton, R. I.; Vermoortele, F.; Maes, M.; de Vos, D.; Millange, F. J. Mater. Chem. 2012, 24, 2781.
[65] Yang, C. X.; Liu, S. S.; Wang, H. F.; Wang, S. W.; Yan, X. P. Analyst 2012, 137, 133.
[66] Zhang, M.; Zhang, J.; Zhang, Y.; Wang, B.; Xie, S.; Yuan, L. J. Chromatogr. A 2014, 1325, 163.
[67] Fu, Y.; Yang, C.; Yan, X. J. Chromatogr. A 2013, 1274, 137.
[68] Zhang, X.; Han, Q.; Ding, M. RSC Adv. 2015, 5, 1043.
[69] Qin, W.; Silvestre, M. E.; Li, Y.; Franzreb, M. J. Chromatogr. A 2016, 1432, 84.
[70] Nong, R. Y.; Kong, J.; Zhang, J. H.; Chen, L.; Tang, B.; Xie, S. M.; Yuan, L. M. Chem. J. Chin. Univ. 2016, 37, 19. (农蕊瑜, 孔娇, 章俊辉, 陈玲, 汤波, 谢生明, 袁黎明, 高等学校化学学报, 2016, 37, 19.)
[71] Qin, W.; Silvestre, M. E.; Brenner-Weiss, G.; Wang, Z.; Schmitt, S.; Hübner, J.; Franzreb, M. Sep. Purif. Technol. 2015, 156, 249.
[72] Yang, F.; Yang, C.; Yan, X. Talanta 2015, 137, 136.
[73] Fu, Y.; Yang, C.; Yan, X. Langmuir 2012, 28, 6794.
[74] He, Y. P.; Tan, Y. X.; Zhang, J. Acta Chim. Sinica 2014, 72, 1228. (何燕萍, 谭衍曦, 张健, 化学学报, 2014, 72, 1228.)
[75] Qi, X. Y.; Li, X. J.; Bai, Y.; Liu, H. W. Chin. J. Chrom. 2016, 34, 10. (祁晓月, 李先江, 白玉, 刘虎威, 色谱, 2016, 34, 10.)
[76] Shu, L.; Chen, S.; Zhao, W.; Bai, Y.; Ma, X.; Li, X.; Li, J.; Somsundaran, P. J. Sep. Sci. 2016, 39, 3163.
[77] Yan, Z.; Zheng, J.; Chen, J.; Tong, P.; Lu, M.; Lin, Z.; Zhang, L. J. Chromatogr. A 2014, 1366, 45.
[78] Fu, Y.; Yang, C.; Yan, X. Chem.-Eur. J. 2013, 19, 13484.
[79] Padmanaban, M.; Mueller, P.; Lieder, C.; Gedrich, K.; Gruenker, R.; Bon, V.; Senkovska, I.; Baumgaertner, S.; Opelt, S.; Paasch, S.; Brunner, E.; Glorius, F.; Klemm, E.; Kaskel, S. Chem. Commun. 2011, 47, 12089.
[80] Nuzhdin, A. L.; Dybtsev, D. N.; Bryliakov, K. P.; Talsi, E. P.; Fedin, V. P. J. Am. Chem. Soc. 2007, 129, 12958.
[81] Tanaka, K.; Muraoka, T.; Hirayama, D.; Ohnish, A. Chem. Commun. 2012, 48, 8577.
[82] Zhang, M.; Pu, Z.; Chen, X.; Gong, X.; Zhu, A.; Yuan, L. Chem. Commun. 2013, 49, 5201.
[83] Kuang, X.; Ma, Y.; Su, H.; Zhang, J.; Dong, Y.; Tang, B. Anal. Chem. 2014, 86, 1277.
[84] Yuan, L. J. Chromatogr. A 2014, 1363, 137.
[85] Zhang, M.; Xue, X.; Zhang, J.; Xie, S.; Zhang, Y.; Yuan, L. Anal. Methods 2014, 6, 341.
[86] Hailili, R.; Wang, L.; Qy, J.; Yao, R.; Zhang, X.; Liu, H. Inorg. Chem. 2015, 54, 3713.
[87] Tanaka, K.; Muraoka, T.; Otubo, Y.; Takahashi, H.; Ohnishi, A. RSC Adv. 2016, 6, 21293.
[88] Tanaka, K.; Hotta, N.; Nagase, S.; Yoza, K. New J. Chem. 2016, 40, 4891.
[89] Dai, Q.; Ma, J.; Ma, S.; Wang, S.; Li, L.; Zhu, X.; Qiao, X. ACS Appl. Mater. Inter. 2016, 8, 21632.
[90] Chen, L.; Ou, J.; Wang, H.; Liu, Z.; Ye, M.; Zou, H. ACS Appl. Mater. Inter. 2016, 8, 20292.
[91] Srivastava, M.; Roy, P. K.; Ramanan, A. RSC Adv. 2016, 6, 13426.