化学学报 ›› 1955, Vol. 21 ›› Issue (3): 281-284. 上一篇    下一篇

论文

极化滴定儀

钱人元1,2, 李郁芬1,2, 沈寿彭1,2   

  1. 1. 中国科学院有机化学研究所;
    2. 復旦大学化学系
  • 投稿日期:1955-05-18 发布日期:2013-06-04

A POLARIZATION REDOX TITRIMETER

CHIEN JEN-YUAN1,2, LEE YUH-FUN1,2, SHEN SHOW-PENG1,2   

  1. Institute of Organic Chemistry,Academia Sinica, Fu-Tan University
  • Received:1955-05-18 Published:2013-06-04

1.介紹了一種用電子管線路的極化滴定儀的裝置和使用,其靈敏度和極化電壓均可調節.2.用I2對S2O3=和Cr2O7=對Fe++的滴定來試驗這滴定儀,得到满意的結果,終點指示靈敏準確,可復演性很好,可供氧化還原滴定的使用.

An electronic trimeter for dead-srtop is here described.The circuit consists of a pentode D.C.amplifier and a cathode-ray tuning indicator.Adjustable porizing voltages(0.1-0.4V) for Pt electrodes are provided and the instrument has adjustable current sensitivity.It has been tested by the titration of Ⅰ2 vs.S2O3= and that of Cr2O7= vs.Fe++ in H2S04 and in HCI.Results show that the end-point indication is sharp, sensitive and accurate.This titrimeter is expected to be applicable to most redox utrations.