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化学学报
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化学学报 ›› 1961, Vol. 27 ›› Issue (2): 163-165. 上一篇    

亚铊离子与乙酸根的络合物的极谱研究

白明彰1, 章健民1, 胡惠容2, 张继先2   

  1. 1. 内蒙古农牧学院;
    2. 内蒙古医学院
  • 投稿日期:1960-07-21 发布日期:2013-06-03

A POLAROGRAPHIC STUDY OF THALLOUS ACETATE COMPLEXES

PAI MING-CHANG1, CHANG CHIEN-MIN1, HU HUI-JUNG2, CHANG KYI-HSIEN2   

  1. 1. Agriculture College, Inner Mongolia;
    2. Medical College, Inner Mongolia
  • Received:1960-07-21 Published:2013-06-03

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536

被引次数

2

采用蒋洪圻和徐光宪的处理方法,用极谱法研究了亚铊离子和乙酸根的络合,得到TlAc和Tl(Ac)2-的逐级稳定常数分别为:K1=0.0661,K2=0.178(25℃,μ=3.00,用NaClO4维持).

The half-wave potential of the thallous ion was determined at 250C in sodium per-chlorate-sodium acetate mixtures over the range of 0-2.0 M sodium acetate at an ionic strength of 3.00.From the data, the existence of Tl(Ac)2- was revealed, in addition to the species TIAc and Tl+ as found by previous investigators[1,2].The successive stability conslants were found to be: K1=0.0661۪.01, K2=0.178۪.03，where Ki=[MLi]/[M][L]i.