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化学学报
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化学学报 ›› 1964, Vol. 30 ›› Issue (2): 139-145. 上一篇    下一篇

论文

中国乌头之研究Ⅴ.雪上一枝篙中的生物碱

朱任宏1, 方圣鼎1, 黄伟光2   

  1. 1. 中国科学院药物研究所;
    2. 中国科学院昆明植物研究所
  • 投稿日期:1963-04-15 发布日期:2013-06-03

THE ALKALOIDS OF CHINESE DRUG,ACONITUM SPP.Ⅴ. ALKALOIDS FROM HYE-SHENG-YI-ZHI-GAO. VAR. HOMOTRICHUM W. T. WANG ACONITUM BULLATIFOLIUM LÉVL.

CHU JEN-HUNG1, FANG SHENG-DIN1, HUANG WEI-GUANG2   

  1. Institute of Materia Medica, Academia Sinica
  • Received:1963-04-15 Published:2013-06-03

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从云南省东川县产的雪上一枝篙(Aconitum bullatifolium Lévl.var.homotrichum WT.Wang)中共分得四种生物碱.一枝篙甲素定为C21H31O2N[熔点251-253°,[α]D27=-56°(c 0.4,甲醇)],是一不饱和的叔胺碱,含二个羟基和一个氮乙烷基.一枝篙乙素定为C24H39O6N[熔点158-159°,[α]D21=+21.82°(c 1.65,甲醇)],含羟基、甲氧基各三及氮乙烷基一.一枝篙丙素为C26H41O7N[熔点220°.硝酸盐熔点197-198°,[α]D=-7°(c 7.18,水)],含二个羟基,三个甲氧基和一个氮乙烷基.

Four alkaloids have been isolated from the Chinese drug,Hye-sheng-yi-zhi-gao(Aconitum bullatifolium Lévl.var.homotrichum,W.T.Wang),and provisionally named as Bullatine A,B,C and D respectively.The Bullatiae A,C21H31O2N,m.p.251-253°,[a]D27=-550 (methanol),was found to be an unsaturated base with two hydroxyl and one ethylimino groups.