化学学报 ›› 1983, Vol. 41 ›› Issue (10): 939-945. 上一篇    下一篇

研究论文

多元酚的氰乙基和乙氧羰乙基化 I.

胡宏纹;陈伟兴;龚维毅   

  1. 南京大学化学系
  • 发布日期:1983-10-15

Cyanoethylation and carbethoxyethylation of polyhydric phenols I.

HU HONGWEN;CHEN WEIXING;GONG WEIYI   

  • Published:1983-10-15

关键词: 多元酚, 氰化, 乙基化, 乙基化, 乙氧羰基

In the presence of alkoxide, resorcinol, methyl and nitro substituted resorcinol give C-polycyanoethyl-substituted products. When the 2-, 4- and 6-positions were occupied the O-cyanoethylation could occur. In the reaction of 2-nitroresorcinol with ethyl acrylate two β-carbethoxyethyl groups are introduced in a similar way to the 4-and 6-positions. The carbethoxyethylation products of resorcinol and 2-methylresorcinol lose ethyl alcohol during distillation giving the corresponding lactones.

Key words: POLYHYDRIC PHENOL, CYANIDATION, ETHYLATION, ETHYLATION, CARBETHOXY GROUP

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