化学学报 ›› 1987, Vol. 45 ›› Issue (6): 525-529.    下一篇

研究论文

开环夹心化合物 VII: 二(2,4-二甲基戊二烯)羰基钒的合成及其低温X射线结构分析

杨光弟;刘举正;樊玉国;梁映秋   

  1. 吉林大学理论化学研究所
  • 发布日期:1987-06-15

Open sandwith compounds VII: The synthesis of bis(2,4-dimethylpentadienyl)vanadium carbonyl and its structure analysis by low temperature X-ray diffraction method

YANG GUANGDI;LIU JUZHENG;FAN YUGUO;LIANG YINGQIU   

  • Published:1987-06-15

关键词: X射线衍射分析, 晶胞, 有机过渡金属化合物, 结构分析, 羰基化合物, 钒化合物, 戊二烯 P, 夹心化合物, 开环

The title compound (I) was prepared from 2,4-dimethylpentadienyl potassium and VCl3?THF. The crystal structures of I was determine at -60?

Key words: X-RAY DIFFRACTION ANALYSIS, UNIT CELL, ORGANO TRANSITION METAL COMPOUNDS, STRUCTURAL ANALYSIS, CARBONYL COMPOUNDS, VANADIUM COMPOUNDS, PENTADIENE P, SANDWICH COMPOUNDS, OPEN CYCLE

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